1,4-anti induction in C-glycosylation of pentose glycals

Seijiro Hosokawa, Bettina Kirschbaum, Minoru Isobe

Research output: Contribution to journalArticle

67 Citations (Scopus)

Abstract

The C-glycosylation of pentose glycals with silylacetylenes or allylsilanes via oxocarbenium ion intermediates proceeded under high regio- and stereoselectivity giving the 1,4-anti products as the predominant products.

Original languageEnglish
Pages (from-to)1917-1920
Number of pages4
JournalTetrahedron Letters
Volume39
Issue number14
DOIs
Publication statusPublished - 1998 Apr 2
Externally publishedYes

Fingerprint

Glycosylation
Pentoses
Stereoselectivity
Regioselectivity
Ions
allylsilane

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

1,4-anti induction in C-glycosylation of pentose glycals. / Hosokawa, Seijiro; Kirschbaum, Bettina; Isobe, Minoru.

In: Tetrahedron Letters, Vol. 39, No. 14, 02.04.1998, p. 1917-1920.

Research output: Contribution to journalArticle

Hosokawa, Seijiro ; Kirschbaum, Bettina ; Isobe, Minoru. / 1,4-anti induction in C-glycosylation of pentose glycals. In: Tetrahedron Letters. 1998 ; Vol. 39, No. 14. pp. 1917-1920.
@article{f42e2de1acc04b5a922aaa3772db2615,
title = "1,4-anti induction in C-glycosylation of pentose glycals",
abstract = "The C-glycosylation of pentose glycals with silylacetylenes or allylsilanes via oxocarbenium ion intermediates proceeded under high regio- and stereoselectivity giving the 1,4-anti products as the predominant products.",
author = "Seijiro Hosokawa and Bettina Kirschbaum and Minoru Isobe",
year = "1998",
month = "4",
day = "2",
doi = "10.1016/S0040-4039(98)00047-1",
language = "English",
volume = "39",
pages = "1917--1920",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "14",

}

TY - JOUR

T1 - 1,4-anti induction in C-glycosylation of pentose glycals

AU - Hosokawa, Seijiro

AU - Kirschbaum, Bettina

AU - Isobe, Minoru

PY - 1998/4/2

Y1 - 1998/4/2

N2 - The C-glycosylation of pentose glycals with silylacetylenes or allylsilanes via oxocarbenium ion intermediates proceeded under high regio- and stereoselectivity giving the 1,4-anti products as the predominant products.

AB - The C-glycosylation of pentose glycals with silylacetylenes or allylsilanes via oxocarbenium ion intermediates proceeded under high regio- and stereoselectivity giving the 1,4-anti products as the predominant products.

UR - http://www.scopus.com/inward/record.url?scp=0032473853&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032473853&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(98)00047-1

DO - 10.1016/S0040-4039(98)00047-1

M3 - Article

AN - SCOPUS:0032473853

VL - 39

SP - 1917

EP - 1920

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 14

ER -