1,4-anti induction in C-glycosylation of pentose glycals

Seijiro Hosokawa; Bettina Kirschbaum; Minoru Isobe

doi:10.1016/S0040-4039(98)00047-1

1,4-anti induction in C-glycosylation of pentose glycals

Seijiro Hosokawa, Bettina Kirschbaum, Minoru Isobe

Research output: Contribution to journal › Article › peer-review

67 Citations (Scopus)

Abstract

The C-glycosylation of pentose glycals with silylacetylenes or allylsilanes via oxocarbenium ion intermediates proceeded under high regio- and stereoselectivity giving the 1,4-anti products as the predominant products.

Original language	English
Pages (from-to)	1917-1920
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	14
DOIs	https://doi.org/10.1016/S0040-4039(98)00047-1
Publication status	Published - 1998 Apr 2
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "1,4-anti induction in C-glycosylation of pentose glycals",

abstract = "The C-glycosylation of pentose glycals with silylacetylenes or allylsilanes via oxocarbenium ion intermediates proceeded under high regio- and stereoselectivity giving the 1,4-anti products as the predominant products.",

author = "Seijiro Hosokawa and Bettina Kirschbaum and Minoru Isobe",

year = "1998",

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AU - Hosokawa, Seijiro

AU - Kirschbaum, Bettina

AU - Isobe, Minoru

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Y1 - 1998/4/2

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AB - The C-glycosylation of pentose glycals with silylacetylenes or allylsilanes via oxocarbenium ion intermediates proceeded under high regio- and stereoselectivity giving the 1,4-anti products as the predominant products.

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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