TY - JOUR
T1 - 2-{[2,2-Bis(diethylamino)ethan-2-yliumthioyl]sulfanyl}-1, 1-bis-(diethylamino)-ethylium bis(perchlorate)
AU - Ohno, Keiji
AU - Sugaya, Tomoaki
AU - Fujihara, Takashi
AU - Nagasawa, Akira
PY - 2012/9
Y1 - 2012/9
N2 - The title salt, C20H42N4S2 2+·2ClO4
-, was obtained from the reaction of bis-(diethyl-amino)-carbeniumdithio-carboxylate, (Et 2N)2C2S2, with Fe(ClO 4)2·6H2O in CH2Cl 2. The title compound, in which one of the S atoms of (Et 2N)2C2S2 is bound to a 1,1-bis-(diethyl-amino)-ethane moiety, has two carbenium C atoms, and the charge compensation is provided by two perchlorate anions. The N2C - CS2 bond length is 1.512 (4) Å, corresponding to a C - C single bond, and the dihedral angle between N2C- and -CS2 planes [72.0 (2)°] is smaller than that of (Et2N)2C 2S2 [82.0 (1)°]. The crystal structure features C - H⋯S hydrogen bonds.
AB - The title salt, C20H42N4S2 2+·2ClO4
-, was obtained from the reaction of bis-(diethyl-amino)-carbeniumdithio-carboxylate, (Et 2N)2C2S2, with Fe(ClO 4)2·6H2O in CH2Cl 2. The title compound, in which one of the S atoms of (Et 2N)2C2S2 is bound to a 1,1-bis-(diethyl-amino)-ethane moiety, has two carbenium C atoms, and the charge compensation is provided by two perchlorate anions. The N2C - CS2 bond length is 1.512 (4) Å, corresponding to a C - C single bond, and the dihedral angle between N2C- and -CS2 planes [72.0 (2)°] is smaller than that of (Et2N)2C 2S2 [82.0 (1)°]. The crystal structure features C - H⋯S hydrogen bonds.
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U2 - 10.1107/S1600536812035453
DO - 10.1107/S1600536812035453
M3 - Article
C2 - 22969636
AN - SCOPUS:84865725063
SN - 1600-5368
VL - 68
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 9
ER -