3,4'-Bis[bis(t-butyl- and methoxy-phenyl)amino]stilbene bis(cation radical)s and their electrochemical and magnetic properties

Tsuyoshi Michinobu, Eishun Tsuchida, Hiroyuki Nishide

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Abstract

3,4'-Bis[bis(p-t-butylphenyl)amino]stilbene 1a and 3,4'-bis[bis(p- methoxyphenyl)amino]stilbene 1b were synthesized. The oxidation of 1 was analyzed by electrochemical measurements, which revealed the reversible formation of the bis(cation radical) 2 via a two-electron transfer reaction. The chemical oxidation of 1 with NOBF4 also gave the bis(cation radical) 2; UV/vis and ESR spectroscopies supported aminium radical formation without any side reaction. Magnetization, magnetic susceptibility, and the ESR ΔM(s) = ±2 signal of the biradicals indicated triplet ground states with a large triplet-singlet energy gap.

Original languageEnglish
Pages (from-to)1021-1027
Number of pages7
JournalBulletin of the Chemical Society of Japan
Volume73
Issue number4
DOIs
Publication statusPublished - 2000 Apr

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ASJC Scopus subject areas

  • Chemistry(all)

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