3.7 Intercalation of n-Alkylamines into Perovskite-related Layered Niobic Acid HBiNb2O7·nH2O

Teruyuki Nakato, Masato Nakade, Kazuyuki Kuroda, Chuzo Kato

    Research output: Contribution to journalArticle

    7 Citations (Scopus)

    Abstract

    n-Alkylammonium-H x BiNb2O7 intercalation compounds were synthesized by the reaction of perovskite-related layered oxide HBiNb2O7·nH2O with n-alkylamines. HBiNb2O7·nH2O was not completely converted to the intercalation compounds except for the methylammonium-intercalate. The intercalating capability of HBiNb2O7·nH2O was much lower than those of other previously reported perovskite-related layered niobates such as HCa2Nb3O10. The poor reactivity was assumed to be related to unusual irreversible dehydrating behavior of HBiNb2O7·nH2O. On the other hand, the interlayer structure was similar to that of the n-alkylammonium-H x Ca2Nb3O10 intercalates in contrast to the difference in the reactivity.

    Original languageEnglish
    Pages (from-to)285-290
    Number of pages6
    JournalStudies in Surface Science and Catalysis
    Volume90
    Issue numberC
    DOIs
    Publication statusPublished - 1994

    Fingerprint

    Intercalation compounds
    Intercalation
    intercalation
    Perovskite
    reactivity
    acids
    Acids
    niobates
    Oxides
    interlayers
    oxides
    perovskite
    methylamine

    ASJC Scopus subject areas

    • Condensed Matter Physics
    • Catalysis
    • Physical and Theoretical Chemistry
    • Materials Chemistry
    • Surfaces, Coatings and Films

    Cite this

    3.7 Intercalation of n-Alkylamines into Perovskite-related Layered Niobic Acid HBiNb2O7·nH2O. / Nakato, Teruyuki; Nakade, Masato; Kuroda, Kazuyuki; Kato, Chuzo.

    In: Studies in Surface Science and Catalysis, Vol. 90, No. C, 1994, p. 285-290.

    Research output: Contribution to journalArticle

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    title = "3.7 Intercalation of n-Alkylamines into Perovskite-related Layered Niobic Acid HBiNb2O7·nH2O",
    abstract = "n-Alkylammonium-H x BiNb2O7 intercalation compounds were synthesized by the reaction of perovskite-related layered oxide HBiNb2O7·nH2O with n-alkylamines. HBiNb2O7·nH2O was not completely converted to the intercalation compounds except for the methylammonium-intercalate. The intercalating capability of HBiNb2O7·nH2O was much lower than those of other previously reported perovskite-related layered niobates such as HCa2Nb3O10. The poor reactivity was assumed to be related to unusual irreversible dehydrating behavior of HBiNb2O7·nH2O. On the other hand, the interlayer structure was similar to that of the n-alkylammonium-H x Ca2Nb3O10 intercalates in contrast to the difference in the reactivity.",
    author = "Teruyuki Nakato and Masato Nakade and Kazuyuki Kuroda and Chuzo Kato",
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    T1 - 3.7 Intercalation of n-Alkylamines into Perovskite-related Layered Niobic Acid HBiNb2O7·nH2O

    AU - Nakato, Teruyuki

    AU - Nakade, Masato

    AU - Kuroda, Kazuyuki

    AU - Kato, Chuzo

    PY - 1994

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    N2 - n-Alkylammonium-H x BiNb2O7 intercalation compounds were synthesized by the reaction of perovskite-related layered oxide HBiNb2O7·nH2O with n-alkylamines. HBiNb2O7·nH2O was not completely converted to the intercalation compounds except for the methylammonium-intercalate. The intercalating capability of HBiNb2O7·nH2O was much lower than those of other previously reported perovskite-related layered niobates such as HCa2Nb3O10. The poor reactivity was assumed to be related to unusual irreversible dehydrating behavior of HBiNb2O7·nH2O. On the other hand, the interlayer structure was similar to that of the n-alkylammonium-H x Ca2Nb3O10 intercalates in contrast to the difference in the reactivity.

    AB - n-Alkylammonium-H x BiNb2O7 intercalation compounds were synthesized by the reaction of perovskite-related layered oxide HBiNb2O7·nH2O with n-alkylamines. HBiNb2O7·nH2O was not completely converted to the intercalation compounds except for the methylammonium-intercalate. The intercalating capability of HBiNb2O7·nH2O was much lower than those of other previously reported perovskite-related layered niobates such as HCa2Nb3O10. The poor reactivity was assumed to be related to unusual irreversible dehydrating behavior of HBiNb2O7·nH2O. On the other hand, the interlayer structure was similar to that of the n-alkylammonium-H x Ca2Nb3O10 intercalates in contrast to the difference in the reactivity.

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