A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc

Takanori Shibata; Hayami Tabira; Kenso Soai

doi:10.1039/a707315a

A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc

Takanori Shibata^*, Hayami Tabira, Kenso Soai

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Enantioselective cyclopropylation of various aldehydes proceeds using dicyclopropylzinc in the presence of a catalytic amount of chiral amino alcohol or thiophosphoramidate with Ti(OPr¹)₄ to provide enantiomerically enriched cyclopropyl alkanols (up to 96.6% ee).

Original language	English
Pages (from-to)	177-178
Number of pages	2
Journal	Journal of the Chemical Society - Perkin Transactions 1
Issue number	2
DOIs	https://doi.org/10.1039/a707315a
Publication status	Published - 1998 Jan 21
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1039/a707315a

Cite this

@article{01d92ae394e7424c832b202b72e17c9a,

title = "A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc",

abstract = "Enantioselective cyclopropylation of various aldehydes proceeds using dicyclopropylzinc in the presence of a catalytic amount of chiral amino alcohol or thiophosphoramidate with Ti(OPr1)4 to provide enantiomerically enriched cyclopropyl alkanols (up to 96.6% ee).",

author = "Takanori Shibata and Hayami Tabira and Kenso Soai",

year = "1998",

month = jan,

day = "21",

doi = "10.1039/a707315a",

language = "English",

pages = "177--178",

journal = "Journal of the Chemical Society. Perkin Transactions 1",

issn = "1470-4358",

publisher = "Chemical Society",

number = "2",

}

TY - JOUR

T1 - A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc

AU - Shibata, Takanori

AU - Tabira, Hayami

AU - Soai, Kenso

PY - 1998/1/21

Y1 - 1998/1/21

N2 - Enantioselective cyclopropylation of various aldehydes proceeds using dicyclopropylzinc in the presence of a catalytic amount of chiral amino alcohol or thiophosphoramidate with Ti(OPr1)4 to provide enantiomerically enriched cyclopropyl alkanols (up to 96.6% ee).

AB - Enantioselective cyclopropylation of various aldehydes proceeds using dicyclopropylzinc in the presence of a catalytic amount of chiral amino alcohol or thiophosphoramidate with Ti(OPr1)4 to provide enantiomerically enriched cyclopropyl alkanols (up to 96.6% ee).

UR - http://www.scopus.com/inward/record.url?scp=33748591596&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33748591596&partnerID=8YFLogxK

U2 - 10.1039/a707315a

DO - 10.1039/a707315a

M3 - Article

AN - SCOPUS:33748591596

SP - 177

EP - 178

JO - Journal of the Chemical Society. Perkin Transactions 1

JF - Journal of the Chemical Society. Perkin Transactions 1

SN - 1470-4358

IS - 2

ER -

A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this