A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc

Takanori Shibata, Hayami Tabira, Kenso Soai

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Enantioselective cyclopropylation of various aldehydes proceeds using dicyclopropylzinc in the presence of a catalytic amount of chiral amino alcohol or thiophosphoramidate with Ti(OPr1)4 to provide enantiomerically enriched cyclopropyl alkanols (up to 96.6% ee).

Original languageEnglish
Pages (from-to)177-178
Number of pages2
JournalJournal of the Chemical Society - Perkin Transactions 1
Issue number2
Publication statusPublished - 1998 Jan 21
Externally publishedYes

Fingerprint

Amino Alcohols
Aldehydes

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc. / Shibata, Takanori; Tabira, Hayami; Soai, Kenso.

In: Journal of the Chemical Society - Perkin Transactions 1, No. 2, 21.01.1998, p. 177-178.

Research output: Contribution to journalArticle

@article{01d92ae394e7424c832b202b72e17c9a,
title = "A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc",
abstract = "Enantioselective cyclopropylation of various aldehydes proceeds using dicyclopropylzinc in the presence of a catalytic amount of chiral amino alcohol or thiophosphoramidate with Ti(OPr1)4 to provide enantiomerically enriched cyclopropyl alkanols (up to 96.6{\%} ee).",
author = "Takanori Shibata and Hayami Tabira and Kenso Soai",
year = "1998",
month = "1",
day = "21",
language = "English",
pages = "177--178",
journal = "Journal of the Chemical Society. Perkin Transactions 1",
issn = "1470-4358",
publisher = "Chemical Society",
number = "2",

}

TY - JOUR

T1 - A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc

AU - Shibata, Takanori

AU - Tabira, Hayami

AU - Soai, Kenso

PY - 1998/1/21

Y1 - 1998/1/21

N2 - Enantioselective cyclopropylation of various aldehydes proceeds using dicyclopropylzinc in the presence of a catalytic amount of chiral amino alcohol or thiophosphoramidate with Ti(OPr1)4 to provide enantiomerically enriched cyclopropyl alkanols (up to 96.6% ee).

AB - Enantioselective cyclopropylation of various aldehydes proceeds using dicyclopropylzinc in the presence of a catalytic amount of chiral amino alcohol or thiophosphoramidate with Ti(OPr1)4 to provide enantiomerically enriched cyclopropyl alkanols (up to 96.6% ee).

UR - http://www.scopus.com/inward/record.url?scp=33748591596&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33748591596&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33748591596

SP - 177

EP - 178

JO - Journal of the Chemical Society. Perkin Transactions 1

JF - Journal of the Chemical Society. Perkin Transactions 1

SN - 1470-4358

IS - 2

ER -