A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc

Takanori Shibata; Hayami Tabira; Kenso Soai

doi:10.1039/a707315a

A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc

Takanori Shibata, Hayami Tabira, Kenso Soai

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Enantioselective cyclopropylation of various aldehydes proceeds using dicyclopropylzinc in the presence of a catalytic amount of chiral amino alcohol or thiophosphoramidate with Ti(OPr¹)₄ to provide enantiomerically enriched cyclopropyl alkanols (up to 96.6% ee).

Original language	English
Pages (from-to)	177-178
Number of pages	2
Journal	Journal of the Chemical Society - Perkin Transactions 1
Issue number	2
DOIs	https://doi.org/10.1039/a707315a
Publication status	Published - 1998 Jan 21
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1039/a707315a

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abstract = "Enantioselective cyclopropylation of various aldehydes proceeds using dicyclopropylzinc in the presence of a catalytic amount of chiral amino alcohol or thiophosphoramidate with Ti(OPr1)4 to provide enantiomerically enriched cyclopropyl alkanols (up to 96.6% ee).",

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