A cyclic tetramer of [Ag(1,4,7-trithiacyclononane)]+, cyclo-tetrakis(μ-1,4,7-trithiacyclononane-κ3S1,S 4,S7: κS1)tetrasilver(I) tetrakis(trifluoromethanesulfonate) nitromethane disolvate

Tadashi Yamaguchi, Fumie Yamazaki, Tasuku Ito

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

(1,4,7-Trithiacyclononane) silver trifluoromethanesulfonate crystallizes in a tetrameric form from nitromethane, to give the title compound, [Ag4(C6H12S3)4](CF3 SO3)4·2CH3NO2. The complex cation consists of four [AgL]+ units (L is 1,4,7-trithiacyclononane), with four Ag-S-Ag bridges forming a cyclic tetramer. The almost planar Ag4S4 ring takes an octagonal form.

Original languageEnglish
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume58
Issue number4
DOIs
Publication statusPublished - 2002 Apr
Externally publishedYes

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ethyl-2-methylthio-4-methyl-5-pyrimidine carboxylate
nitromethane
silver
cations
rings
Cations
trifluoromethanesulfonic acid
trithiacyclononane

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

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title = "A cyclic tetramer of [Ag(1,4,7-trithiacyclononane)]+, cyclo-tetrakis(μ-1,4,7-trithiacyclononane-κ3S1,S 4,S7: κS1)tetrasilver(I) tetrakis(trifluoromethanesulfonate) nitromethane disolvate",
abstract = "(1,4,7-Trithiacyclononane) silver trifluoromethanesulfonate crystallizes in a tetrameric form from nitromethane, to give the title compound, [Ag4(C6H12S3)4](CF3 SO3)4·2CH3NO2. The complex cation consists of four [AgL]+ units (L is 1,4,7-trithiacyclononane), with four Ag-S-Ag bridges forming a cyclic tetramer. The almost planar Ag4S4 ring takes an octagonal form.",
author = "Tadashi Yamaguchi and Fumie Yamazaki and Tasuku Ito",
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doi = "10.1107/S0108270102001075",
language = "English",
volume = "58",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
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T1 - A cyclic tetramer of [Ag(1,4,7-trithiacyclononane)]+, cyclo-tetrakis(μ-1,4,7-trithiacyclononane-κ3S1,S 4,S7

T2 - κS1)tetrasilver(I) tetrakis(trifluoromethanesulfonate) nitromethane disolvate

AU - Yamaguchi, Tadashi

AU - Yamazaki, Fumie

AU - Ito, Tasuku

PY - 2002/4

Y1 - 2002/4

N2 - (1,4,7-Trithiacyclononane) silver trifluoromethanesulfonate crystallizes in a tetrameric form from nitromethane, to give the title compound, [Ag4(C6H12S3)4](CF3 SO3)4·2CH3NO2. The complex cation consists of four [AgL]+ units (L is 1,4,7-trithiacyclononane), with four Ag-S-Ag bridges forming a cyclic tetramer. The almost planar Ag4S4 ring takes an octagonal form.

AB - (1,4,7-Trithiacyclononane) silver trifluoromethanesulfonate crystallizes in a tetrameric form from nitromethane, to give the title compound, [Ag4(C6H12S3)4](CF3 SO3)4·2CH3NO2. The complex cation consists of four [AgL]+ units (L is 1,4,7-trithiacyclononane), with four Ag-S-Ag bridges forming a cyclic tetramer. The almost planar Ag4S4 ring takes an octagonal form.

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