A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands

Yuji Kikukawa, Yoshiyuki Kuroda, Kosuke Suzuki, Mitsuhiro Hibino, Kazuya Yamaguchi, Noritaka Mizuno

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

By the reaction of TBA4H4[γ-SiW 10O36] (TBA = tetra-n-butylammonium) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag6] 4+ cluster, TBA8[Ag6(γ-H 2SiW10O36)2]·5H2O, could be synthesized, and the molecular structure was determined. This journal is

Original languageEnglish
Pages (from-to)376-378
Number of pages3
JournalChemical Communications
Volume49
Issue number4
DOIs
Publication statusPublished - 2013 Jan 14
Externally publishedYes

Fingerprint

Reducing Agents
Acetone
Molecular structure
Acetates
Ligands
polyoxometalate I

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Kikukawa, Y., Kuroda, Y., Suzuki, K., Hibino, M., Yamaguchi, K., & Mizuno, N. (2013). A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands. Chemical Communications, 49(4), 376-378. https://doi.org/10.1039/c2cc37591e

A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands. / Kikukawa, Yuji; Kuroda, Yoshiyuki; Suzuki, Kosuke; Hibino, Mitsuhiro; Yamaguchi, Kazuya; Mizuno, Noritaka.

In: Chemical Communications, Vol. 49, No. 4, 14.01.2013, p. 376-378.

Research output: Contribution to journalArticle

Kikukawa, Y, Kuroda, Y, Suzuki, K, Hibino, M, Yamaguchi, K & Mizuno, N 2013, 'A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands', Chemical Communications, vol. 49, no. 4, pp. 376-378. https://doi.org/10.1039/c2cc37591e
Kikukawa, Yuji ; Kuroda, Yoshiyuki ; Suzuki, Kosuke ; Hibino, Mitsuhiro ; Yamaguchi, Kazuya ; Mizuno, Noritaka. / A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands. In: Chemical Communications. 2013 ; Vol. 49, No. 4. pp. 376-378.
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