A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands

Yuji Kikukawa; Yoshiyuki Kuroda; Kosuke Suzuki; Mitsuhiro Hibino; Kazuya Yamaguchi; Noritaka Mizuno

doi:10.1039/c2cc37591e

A discrete octahedrally shaped [Ag₆]⁴⁺ cluster encapsulated within silicotungstate ligands

Yuji Kikukawa, Yoshiyuki Kuroda, Kosuke Suzuki, Mitsuhiro Hibino, Kazuya Yamaguchi, Noritaka Mizuno^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

By the reaction of TBA₄H₄[γ-SiW ₁₀O₃₆] (TBA = tetra-n-butylammonium) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag₆] ⁴⁺ cluster, TBA₈[Ag₆(γ-H ₂SiW₁₀O₃₆)₂]·5H₂O, could be synthesized, and the molecular structure was determined. This journal is

Original language	English
Pages (from-to)	376-378
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	4
DOIs	https://doi.org/10.1039/c2cc37591e
Publication status	Published - 2013 Jan 14
Externally published	Yes

ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Catalysis
Chemistry(all)

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10.1039/c2cc37591e

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abstract = "By the reaction of TBA4H4[γ-SiW 10O36] (TBA = tetra-n-butylammonium) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag6] 4+ cluster, TBA8[Ag6(γ-H 2SiW10O36)2]·5H2O, could be synthesized, and the molecular structure was determined. This journal is",

author = "Yuji Kikukawa and Yoshiyuki Kuroda and Kosuke Suzuki and Mitsuhiro Hibino and Kazuya Yamaguchi and Noritaka Mizuno",

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T1 - A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands

AU - Kikukawa, Yuji

AU - Kuroda, Yoshiyuki

AU - Suzuki, Kosuke

AU - Hibino, Mitsuhiro

AU - Yamaguchi, Kazuya

AU - Mizuno, Noritaka

PY - 2013/1/14

Y1 - 2013/1/14

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AB - By the reaction of TBA4H4[γ-SiW 10O36] (TBA = tetra-n-butylammonium) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag6] 4+ cluster, TBA8[Ag6(γ-H 2SiW10O36)2]·5H2O, could be synthesized, and the molecular structure was determined. This journal is

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JO - Chemical Communications

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A discrete octahedrally shaped [Ag₆]⁴⁺ cluster encapsulated within silicotungstate ligands

Abstract

ASJC Scopus subject areas

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