A fundamental study on the molybdenum recovery from the copper smelting slag by slow cooling

Shunsuke Sudo, Takahiko Okura, Chiharu Tokoro

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    Copper smelting slag has been produced in large quantities every year all over the world. The slag contains various value metals, such as molybdenum, iron, copper, and zinc. However, it is difficult to economically recover these metals from the slag since it is rapidly cooled into an amorphous structure in granulation water. On the other hand, a lot of minerals in slags can be crystalized by slow cooling. Then, molybdenum recovery from copper smelting slags was investigated using crystallization by slow cooling under rate controlling and solid/solid separation in this study. A water cooled slag of 0.2 wt% Mo was used as sample. Mo concentration in slag was controlled from 0.2 to 4 wt% by adding MoO3 reagent, heated at 1300 °C for 1 hour in Ar atmosphere by super kanthal furnace, cooled and ground under 125 μm. Pyrite (FeS 2) was added to this slag to achieve reduction atmosphere and sulfurize molybdenum as molybdenum sulfide (MoS2) to achieve 2 or 5 of S/Mo molar ratio. This sample was heated at 1300 °C for 1 hour in Ar atmosphere and slowly cooled at up to 18 °C/min. The slow cooling slag was analysed by XRF, XRD, SEM-EDS, XAFS (XANES) to know selective molybdenum sulfurization and crystallization of minerals including molybdenum sulfide. MoS2 crystal was identified in Mo 2 wt-% slag (S/Mo =5) and 4 wt-% slag (S/Mo = 2, 5) and maximum particle diameter was 150 μm. The ratio of MoS2 to all Mo in slag was determined by XANES analysis, resulted in 95.83 % of MoS2 in Mo 4 wt-% slag (S/Mo = 5). 16.7 wt% Mo concentrate was obtained by flotation after grinding under 125 μm and using PAX and MIBC at pH 6.6.

    Original languageEnglish
    Title of host publicationEuropean Metallurgical Conference, EMC 2013
    Pages689-702
    Number of pages14
    Publication statusPublished - 2013
    Event7th European Metallurgical Conference, EMC 2013 - Weimar
    Duration: 2013 Jun 232013 Jun 26

    Other

    Other7th European Metallurgical Conference, EMC 2013
    CityWeimar
    Period13/6/2313/6/26

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    Keywords

    • Copper slag
    • Molybdenum
    • Pyrite
    • Slow cooling

    ASJC Scopus subject areas

    • Metals and Alloys

    Cite this

    Sudo, S., Okura, T., & Tokoro, C. (2013). A fundamental study on the molybdenum recovery from the copper smelting slag by slow cooling. In European Metallurgical Conference, EMC 2013 (pp. 689-702)