A hybrid lithium oxalate-phosphinate salt

Andrew R. Shaffer, Nihal Deligonul, Daniel Alberto Scherson, John D. Protasiewicz

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The novel organophosphorus-containing lithium salt Li(THF)[(C 2O4)B(O2PPh2)2] (1; THF = tetrahydrofuran) was synthesized and characterized using a variety of spectroscopic techniques. An X-ray structural analysis on crystals of 1 grown from THF reveals a dimeric structure [Li(THF)(C2O4) B(O2PPh2)2]2·THF, whereby the two units of 1 are bridged via P-O⋯Li interactions. Compound 1 displays high air and water stability and is also thermally robust, properties needed of electrolytes for their possible use as electrolytes and/or additives in lithium-ion battery applications.

Original languageEnglish
Pages (from-to)10756-10758
Number of pages3
JournalInorganic Chemistry
Volume49
Issue number23
DOIs
Publication statusPublished - 2010 Dec 6
Externally publishedYes

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'A hybrid lithium oxalate-phosphinate salt'. Together they form a unique fingerprint.

  • Cite this

    Shaffer, A. R., Deligonul, N., Scherson, D. A., & Protasiewicz, J. D. (2010). A hybrid lithium oxalate-phosphinate salt. Inorganic Chemistry, 49(23), 10756-10758. https://doi.org/10.1021/ic1018532