A hybrid lithium oxalate-phosphinate salt

Andrew R. Shaffer, Nihal Deligonul, Daniel Alberto Scherson, John D. Protasiewicz

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The novel organophosphorus-containing lithium salt Li(THF)[(C 2O4)B(O2PPh2)2] (1; THF = tetrahydrofuran) was synthesized and characterized using a variety of spectroscopic techniques. An X-ray structural analysis on crystals of 1 grown from THF reveals a dimeric structure [Li(THF)(C2O4) B(O2PPh2)2]2·THF, whereby the two units of 1 are bridged via P-O⋯Li interactions. Compound 1 displays high air and water stability and is also thermally robust, properties needed of electrolytes for their possible use as electrolytes and/or additives in lithium-ion battery applications.

Original languageEnglish
Pages (from-to)10756-10758
Number of pages3
JournalInorganic Chemistry
Volume49
Issue number23
DOIs
Publication statusPublished - 2010 Dec 6
Externally publishedYes

Fingerprint

Oxalates
oxalates
Lithium
Electrolytes
Salts
lithium
electrolytes
salts
tetrahydrofuran
structural analysis
Structural analysis
electric batteries
Display devices
X rays
Crystals
Water
air
Air
water
crystals

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Shaffer, A. R., Deligonul, N., Scherson, D. A., & Protasiewicz, J. D. (2010). A hybrid lithium oxalate-phosphinate salt. Inorganic Chemistry, 49(23), 10756-10758. https://doi.org/10.1021/ic1018532

A hybrid lithium oxalate-phosphinate salt. / Shaffer, Andrew R.; Deligonul, Nihal; Scherson, Daniel Alberto; Protasiewicz, John D.

In: Inorganic Chemistry, Vol. 49, No. 23, 06.12.2010, p. 10756-10758.

Research output: Contribution to journalArticle

Shaffer, AR, Deligonul, N, Scherson, DA & Protasiewicz, JD 2010, 'A hybrid lithium oxalate-phosphinate salt', Inorganic Chemistry, vol. 49, no. 23, pp. 10756-10758. https://doi.org/10.1021/ic1018532
Shaffer AR, Deligonul N, Scherson DA, Protasiewicz JD. A hybrid lithium oxalate-phosphinate salt. Inorganic Chemistry. 2010 Dec 6;49(23):10756-10758. https://doi.org/10.1021/ic1018532
Shaffer, Andrew R. ; Deligonul, Nihal ; Scherson, Daniel Alberto ; Protasiewicz, John D. / A hybrid lithium oxalate-phosphinate salt. In: Inorganic Chemistry. 2010 ; Vol. 49, No. 23. pp. 10756-10758.
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