A new classification of alkali and alkaline earth catalysts for gasification of carbon

Masahiko Matsukata; Eiichi Kikuchi; Yoshiro Morita

doi:10.1016/0016-2361(92)90136-C

A new classification of alkali and alkaline earth catalysts for gasification of carbon

Masahiko Matsukata^*, Eiichi Kikuchi, Yoshiro Morita

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The variations in the amounts of alkali and alkaline earth species actually existing on the surface of carbon black in the courses of heat treatment up to 1123 K and steam gasification at 1073 K were investigated, in order to understand the actual amount of catalyst existing on the surface of carbon in the working state. These gasification catalysts were classified into three groups based on the fact that some of them sunk into the bulk of carbon in the course of heat treatment and some of them vaporized from the surface of carbon. It was found that the migration of species into the bulk of carbon was profoundly associated with the reducibility of their oxide state.

Original language	English
Pages (from-to)	819-823
Number of pages	5
Journal	Fuel
Volume	71
Issue number	7
DOIs	https://doi.org/10.1016/0016-2361(92)90136-C
Publication status	Published - 1992 Jul

Keywords

alkaline earth catalysts
carbon
gasification

ASJC Scopus subject areas

Chemical Engineering(all)
Fuel Technology
Energy Engineering and Power Technology
Organic Chemistry

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10.1016/0016-2361(92)90136-C

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abstract = "The variations in the amounts of alkali and alkaline earth species actually existing on the surface of carbon black in the courses of heat treatment up to 1123 K and steam gasification at 1073 K were investigated, in order to understand the actual amount of catalyst existing on the surface of carbon in the working state. These gasification catalysts were classified into three groups based on the fact that some of them sunk into the bulk of carbon in the course of heat treatment and some of them vaporized from the surface of carbon. It was found that the migration of species into the bulk of carbon was profoundly associated with the reducibility of their oxide state.",

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author = "Masahiko Matsukata and Eiichi Kikuchi and Yoshiro Morita",

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AU - Matsukata, Masahiko

AU - Kikuchi, Eiichi

AU - Morita, Yoshiro

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Y1 - 1992/7

N2 - The variations in the amounts of alkali and alkaline earth species actually existing on the surface of carbon black in the courses of heat treatment up to 1123 K and steam gasification at 1073 K were investigated, in order to understand the actual amount of catalyst existing on the surface of carbon in the working state. These gasification catalysts were classified into three groups based on the fact that some of them sunk into the bulk of carbon in the course of heat treatment and some of them vaporized from the surface of carbon. It was found that the migration of species into the bulk of carbon was profoundly associated with the reducibility of their oxide state.

AB - The variations in the amounts of alkali and alkaline earth species actually existing on the surface of carbon black in the courses of heat treatment up to 1123 K and steam gasification at 1073 K were investigated, in order to understand the actual amount of catalyst existing on the surface of carbon in the working state. These gasification catalysts were classified into three groups based on the fact that some of them sunk into the bulk of carbon in the course of heat treatment and some of them vaporized from the surface of carbon. It was found that the migration of species into the bulk of carbon was profoundly associated with the reducibility of their oxide state.

KW - alkaline earth catalysts

KW - carbon

KW - gasification

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ER -

A new classification of alkali and alkaline earth catalysts for gasification of carbon

Abstract

Keywords

ASJC Scopus subject areas

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