A new one-pot method for α,α-diallylation of ketones based on the palladium-catalyzed reaction of allylic carbonates and allyl β-keto carboxylates under neutral conditions

Isao Shimizu, Yukihiro Ohashi, Jiro Tsuji

    Research output: Contribution to journalArticle

    12 Citations (Scopus)

    Abstract

    A new method for α,α-diallylation of ketones catalyzed by palladium-phosphine complexes under neutral conditions has been developed. Allylation of β-keto carboxylates with allylic carbonates, followed by the decarboxylation-allylation as a one-pot reaction affords diallylated ketones in good yields.

    Original languageEnglish
    Pages (from-to)3865-3868
    Number of pages4
    JournalTetrahedron Letters
    Volume24
    Issue number36
    DOIs
    Publication statusPublished - 1983

      Fingerprint

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

    Cite this