A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation

Takashi Niwa; Masahisa Nakada

doi:10.1021/ja304219s

A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation

Takashi Niwa, Masahisa Nakada

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.

Original language	English
Pages (from-to)	13538-13541
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	33
DOIs	https://doi.org/10.1021/ja304219s
Publication status	Published - 2012 Aug 22

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja304219s

Fingerprint Dive into the research topics of 'A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation'. Together they form a unique fingerprint.

Cite this

@article{61ed5e9f907b47d2a65300791222301c,

title = "A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation",

abstract = "In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.",

author = "Takashi Niwa and Masahisa Nakada",

year = "2012",

month = aug,

day = "22",

doi = "10.1021/ja304219s",

language = "English",

volume = "134",

pages = "13538--13541",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "33",

}

TY - JOUR

T1 - A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation

AU - Niwa, Takashi

AU - Nakada, Masahisa

PY - 2012/8/22

Y1 - 2012/8/22

N2 - In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.

AB - In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.

UR - http://www.scopus.com/inward/record.url?scp=84865439282&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84865439282&partnerID=8YFLogxK

U2 - 10.1021/ja304219s

DO - 10.1021/ja304219s

M3 - Article

C2 - 22861141

AN - SCOPUS:84865439282

VL - 134

SP - 13538

EP - 13541

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 33

ER -

A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this