A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation

Takashi Niwa; Masahisa Nakada

doi:10.1021/ja304219s

A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation

Takashi Niwa, Masahisa Nakada

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.

Original language	English
Pages (from-to)	13538-13541
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	33
DOIs	https://doi.org/10.1021/ja304219s
Publication status	Published - 2012 Aug 22

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja304219s

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abstract = "In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.",

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