A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation

Takashi Niwa, Masahisa Nakada

    Research output: Contribution to journal › Article

    60 Citations (Scopus)

    Abstract

    In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.

    Original languageEnglish
    Pages (from-to)13538-13541
    Number of pages4
    JournalJournal of the American Chemical Society
    Volume134
    Issue number33
    DOIs
    Publication statusPublished - 2012 Aug 22

    Fingerprint

    Epoxidation
    Porphyrins
    Iron
    Alkenes
    Electron energy levels
    Olefins
    Electronic structure
    Ligands
    Electrons
    Temperature

    ASJC Scopus subject areas

    • Chemistry(all)
    • Catalysis
    • Biochemistry
    • Colloid and Surface Chemistry

    Cite this

    A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation. / Niwa, Takashi; Nakada, Masahisa.

    In: Journal of the American Chemical Society, Vol. 134, No. 33, 22.08.2012, p. 13538-13541.

    Research output: Contribution to journal › Article

    Niwa, T & Nakada, M 2012, 'A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation', Journal of the American Chemical Society, vol. 134, no. 33, pp. 13538-13541. https://doi.org/10.1021/ja304219s
    Niwa T, Nakada M. A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation. Journal of the American Chemical Society. 2012 Aug 22;134(33):13538-13541. https://doi.org/10.1021/ja304219s
    Niwa, Takashi ; Nakada, Masahisa. / A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation. In: Journal of the American Chemical Society. 2012 ; Vol. 134, No. 33. pp. 13538-13541.
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