A novel palladium-catalyzed preparative method of α,β-unsaturated ketones and aldehydes from saturated ketones and aldehydes via their silyl enol ethers

Jiro Tsuji, Ichiro Minami, Isao Shimizu

    Research output: Contribution to journalArticle

    60 Citations (Scopus)

    Abstract

    Silyl enol ethers prepared from saturated ketones and aldehydes can be converted to α,β-unsaturated ketones and aldehydes by the reaction of allyl carbonate in the presence of palladium-phosphine complexes as a catalyst. The selection of solvent is crucial and nitriles are most effective as the solvent.

    Original languageEnglish
    Pages (from-to)5635-5638
    Number of pages4
    JournalTetrahedron Letters
    Volume24
    Issue number50
    DOIs
    Publication statusPublished - 1983

    Fingerprint

    phosphine
    Ethers
    Palladium
    Ketones
    Aldehydes
    Acrolein
    Nitriles
    Carbonates
    Catalysts

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

    Cite this

    A novel palladium-catalyzed preparative method of α,β-unsaturated ketones and aldehydes from saturated ketones and aldehydes via their silyl enol ethers. / Tsuji, Jiro; Minami, Ichiro; Shimizu, Isao.

    In: Tetrahedron Letters, Vol. 24, No. 50, 1983, p. 5635-5638.

    Research output: Contribution to journalArticle

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    AU - Shimizu, Isao

    PY - 1983

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