A novel palladium-catalyzed preparative method of α,β-unsaturated ketones and aldehydes from saturated ketones and aldehydes via their silyl enol ethers

Jiro Tsuji; Ichiro Minami; Isao Shimizu

doi:10.1016/S0040-4039(00)94160-1

A novel palladium-catalyzed preparative method of α,β-unsaturated ketones and aldehydes from saturated ketones and aldehydes via their silyl enol ethers

Jiro Tsuji^*, Ichiro Minami, Isao Shimizu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

Silyl enol ethers prepared from saturated ketones and aldehydes can be converted to α,β-unsaturated ketones and aldehydes by the reaction of allyl carbonate in the presence of palladium-phosphine complexes as a catalyst. The selection of solvent is crucial and nitriles are most effective as the solvent.

Original language	English
Pages (from-to)	5635-5638
Number of pages	4
Journal	Tetrahedron Letters
Volume	24
Issue number	50
DOIs	https://doi.org/10.1016/S0040-4039(00)94160-1
Publication status	Published - 1983

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Drug Discovery

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10.1016/S0040-4039(00)94160-1

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title = "A novel palladium-catalyzed preparative method of α,β-unsaturated ketones and aldehydes from saturated ketones and aldehydes via their silyl enol ethers",

abstract = "Silyl enol ethers prepared from saturated ketones and aldehydes can be converted to α,β-unsaturated ketones and aldehydes by the reaction of allyl carbonate in the presence of palladium-phosphine complexes as a catalyst. The selection of solvent is crucial and nitriles are most effective as the solvent.",

author = "Jiro Tsuji and Ichiro Minami and Isao Shimizu",

year = "1983",

doi = "10.1016/S0040-4039(00)94160-1",

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journal = "Tetrahedron Letters",

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number = "50",

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T1 - A novel palladium-catalyzed preparative method of α,β-unsaturated ketones and aldehydes from saturated ketones and aldehydes via their silyl enol ethers

AU - Tsuji, Jiro

AU - Minami, Ichiro

AU - Shimizu, Isao

PY - 1983

Y1 - 1983

N2 - Silyl enol ethers prepared from saturated ketones and aldehydes can be converted to α,β-unsaturated ketones and aldehydes by the reaction of allyl carbonate in the presence of palladium-phosphine complexes as a catalyst. The selection of solvent is crucial and nitriles are most effective as the solvent.

AB - Silyl enol ethers prepared from saturated ketones and aldehydes can be converted to α,β-unsaturated ketones and aldehydes by the reaction of allyl carbonate in the presence of palladium-phosphine complexes as a catalyst. The selection of solvent is crucial and nitriles are most effective as the solvent.

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U2 - 10.1016/S0040-4039(00)94160-1

DO - 10.1016/S0040-4039(00)94160-1

M3 - Article

AN - SCOPUS:0001024999

SN - 0040-4039

VL - 24

SP - 5635

EP - 5638

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 50

ER -

A novel palladium-catalyzed preparative method of α,β-unsaturated ketones and aldehydes from saturated ketones and aldehydes via their silyl enol ethers

Abstract

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