A rechargeable battery based on hydrophilic radical polymer electrode and its green assessment

K. Koshika, M. Kitajima, Kenichi Oyaizu, Hiroyuki Nishide

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A hydrophilic radical polymer electrode-based rechargeable battery was designed along the concept of green chemistry. A hydrophilic radical polymer, poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl vinylether), was synthesized as an electrode-active material; its battery demonstrated a high charging-discharging rate and long cycle life. The combination of the hydrophilic polymer electrode and an aqueous electrolyte for the battery fabrication was expected to provide safety improvements such as a low ignition risk besides the high battery performance. The green characteristics were studied using the "i-Messe," an evaluation method proposed by the committee of the Green Sustainable Chemistry Network, Japan. The electrode-active polymer was evaluated for substantial improvements in disaster safety and health safety.

Original languageEnglish
Pages (from-to)169-174
Number of pages6
JournalGreen Chemistry Letters and Reviews
Volume2
Issue number3
DOIs
Publication statusPublished - 2009

Fingerprint

Secondary batteries
Polymers
electrode
polymer
Electrodes
safety
health and safety
Disasters
electrolyte
Electrolytes
Ignition
Life cycle
disaster
life cycle
Health
Fabrication
battery

Keywords

  • Aqueous electrolyte
  • Radical polymer
  • Redox polymer
  • Safety assessment
  • Secondary battery

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry

Cite this

A rechargeable battery based on hydrophilic radical polymer electrode and its green assessment. / Koshika, K.; Kitajima, M.; Oyaizu, Kenichi; Nishide, Hiroyuki.

In: Green Chemistry Letters and Reviews, Vol. 2, No. 3, 2009, p. 169-174.

Research output: Contribution to journalArticle

@article{be1b98aa5ece48b481574109e29cd56f,
title = "A rechargeable battery based on hydrophilic radical polymer electrode and its green assessment",
abstract = "A hydrophilic radical polymer electrode-based rechargeable battery was designed along the concept of green chemistry. A hydrophilic radical polymer, poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl vinylether), was synthesized as an electrode-active material; its battery demonstrated a high charging-discharging rate and long cycle life. The combination of the hydrophilic polymer electrode and an aqueous electrolyte for the battery fabrication was expected to provide safety improvements such as a low ignition risk besides the high battery performance. The green characteristics were studied using the {"}i-Messe,{"} an evaluation method proposed by the committee of the Green Sustainable Chemistry Network, Japan. The electrode-active polymer was evaluated for substantial improvements in disaster safety and health safety.",
keywords = "Aqueous electrolyte, Radical polymer, Redox polymer, Safety assessment, Secondary battery",
author = "K. Koshika and M. Kitajima and Kenichi Oyaizu and Hiroyuki Nishide",
year = "2009",
doi = "10.1080/17518250903251775",
language = "English",
volume = "2",
pages = "169--174",
journal = "Green Chemistry Letters and Reviews",
issn = "1751-8253",
publisher = "Taylor and Francis Ltd.",
number = "3",

}

TY - JOUR

T1 - A rechargeable battery based on hydrophilic radical polymer electrode and its green assessment

AU - Koshika, K.

AU - Kitajima, M.

AU - Oyaizu, Kenichi

AU - Nishide, Hiroyuki

PY - 2009

Y1 - 2009

N2 - A hydrophilic radical polymer electrode-based rechargeable battery was designed along the concept of green chemistry. A hydrophilic radical polymer, poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl vinylether), was synthesized as an electrode-active material; its battery demonstrated a high charging-discharging rate and long cycle life. The combination of the hydrophilic polymer electrode and an aqueous electrolyte for the battery fabrication was expected to provide safety improvements such as a low ignition risk besides the high battery performance. The green characteristics were studied using the "i-Messe," an evaluation method proposed by the committee of the Green Sustainable Chemistry Network, Japan. The electrode-active polymer was evaluated for substantial improvements in disaster safety and health safety.

AB - A hydrophilic radical polymer electrode-based rechargeable battery was designed along the concept of green chemistry. A hydrophilic radical polymer, poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl vinylether), was synthesized as an electrode-active material; its battery demonstrated a high charging-discharging rate and long cycle life. The combination of the hydrophilic polymer electrode and an aqueous electrolyte for the battery fabrication was expected to provide safety improvements such as a low ignition risk besides the high battery performance. The green characteristics were studied using the "i-Messe," an evaluation method proposed by the committee of the Green Sustainable Chemistry Network, Japan. The electrode-active polymer was evaluated for substantial improvements in disaster safety and health safety.

KW - Aqueous electrolyte

KW - Radical polymer

KW - Redox polymer

KW - Safety assessment

KW - Secondary battery

UR - http://www.scopus.com/inward/record.url?scp=77951715229&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77951715229&partnerID=8YFLogxK

U2 - 10.1080/17518250903251775

DO - 10.1080/17518250903251775

M3 - Article

AN - SCOPUS:77951715229

VL - 2

SP - 169

EP - 174

JO - Green Chemistry Letters and Reviews

JF - Green Chemistry Letters and Reviews

SN - 1751-8253

IS - 3

ER -