Absolute chirality of the γ-polymorph of glycine: Correlation of the absolute structure with the optical rotation

Kazuhiko Ishikawa, Masahito Tanaka, Toshiya Suzuki, Akiko Sekine, Tsuneomi Kawasaki, Kenso Soai, Motoo Shiro, Meir Lahav, Toru Asahi

    Research output: Contribution to journalArticle

    12 Citations (Scopus)

    Abstract

    Crystal specimens of the γ-polymorph of achiral glycine which crystallize in space groups P3 1 and P3 2 as determined by the anomalous X-ray scattering method are shown to be laevorotatory and dextrorotatory, respectively, as determined by optical rotation of the crystals.

    Original languageEnglish
    Pages (from-to)6031-6033
    Number of pages3
    JournalChemical Communications
    Volume48
    Issue number48
    DOIs
    Publication statusPublished - 2012 Jun 18

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    Optical rotation
    Chirality
    Polymorphism
    Glycine
    Amino acids
    Crystals
    X ray scattering

    ASJC Scopus subject areas

    • Metals and Alloys
    • Materials Chemistry
    • Surfaces, Coatings and Films
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Catalysis
    • Chemistry(all)

    Cite this

    Absolute chirality of the γ-polymorph of glycine : Correlation of the absolute structure with the optical rotation. / Ishikawa, Kazuhiko; Tanaka, Masahito; Suzuki, Toshiya; Sekine, Akiko; Kawasaki, Tsuneomi; Soai, Kenso; Shiro, Motoo; Lahav, Meir; Asahi, Toru.

    In: Chemical Communications, Vol. 48, No. 48, 18.06.2012, p. 6031-6033.

    Research output: Contribution to journalArticle

    Ishikawa, K, Tanaka, M, Suzuki, T, Sekine, A, Kawasaki, T, Soai, K, Shiro, M, Lahav, M & Asahi, T 2012, 'Absolute chirality of the γ-polymorph of glycine: Correlation of the absolute structure with the optical rotation', Chemical Communications, vol. 48, no. 48, pp. 6031-6033. https://doi.org/10.1039/c2cc30549f
    Ishikawa, Kazuhiko ; Tanaka, Masahito ; Suzuki, Toshiya ; Sekine, Akiko ; Kawasaki, Tsuneomi ; Soai, Kenso ; Shiro, Motoo ; Lahav, Meir ; Asahi, Toru. / Absolute chirality of the γ-polymorph of glycine : Correlation of the absolute structure with the optical rotation. In: Chemical Communications. 2012 ; Vol. 48, No. 48. pp. 6031-6033.
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    AU - Soai, Kenso

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