Absolute chirality of the γ-polymorph of glycine

Correlation of the absolute structure with the optical rotation

Kazuhiko Ishikawa, Masahito Tanaka, Toshiya Suzuki, Akiko Sekine, Tsuneomi Kawasaki, Kenso Soai, Motoo Shiro, Meir Lahav, Toru Asahi

    Research output: Contribution to journalArticle

    11 Citations (Scopus)

    Abstract

    Crystal specimens of the γ-polymorph of achiral glycine which crystallize in space groups P3 1 and P3 2 as determined by the anomalous X-ray scattering method are shown to be laevorotatory and dextrorotatory, respectively, as determined by optical rotation of the crystals.

    Original languageEnglish
    Pages (from-to)6031-6033
    Number of pages3
    JournalChemical Communications
    Volume48
    Issue number48
    DOIs
    Publication statusPublished - 2012 Jun 18

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    Optical rotation
    Chirality
    Polymorphism
    Glycine
    Amino acids
    Crystals
    X ray scattering

    ASJC Scopus subject areas

    • Metals and Alloys
    • Materials Chemistry
    • Surfaces, Coatings and Films
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Catalysis
    • Chemistry(all)

    Cite this

    Absolute chirality of the γ-polymorph of glycine : Correlation of the absolute structure with the optical rotation. / Ishikawa, Kazuhiko; Tanaka, Masahito; Suzuki, Toshiya; Sekine, Akiko; Kawasaki, Tsuneomi; Soai, Kenso; Shiro, Motoo; Lahav, Meir; Asahi, Toru.

    In: Chemical Communications, Vol. 48, No. 48, 18.06.2012, p. 6031-6033.

    Research output: Contribution to journalArticle

    Ishikawa, K, Tanaka, M, Suzuki, T, Sekine, A, Kawasaki, T, Soai, K, Shiro, M, Lahav, M & Asahi, T 2012, 'Absolute chirality of the γ-polymorph of glycine: Correlation of the absolute structure with the optical rotation', Chemical Communications, vol. 48, no. 48, pp. 6031-6033. https://doi.org/10.1039/c2cc30549f
    Ishikawa, Kazuhiko ; Tanaka, Masahito ; Suzuki, Toshiya ; Sekine, Akiko ; Kawasaki, Tsuneomi ; Soai, Kenso ; Shiro, Motoo ; Lahav, Meir ; Asahi, Toru. / Absolute chirality of the γ-polymorph of glycine : Correlation of the absolute structure with the optical rotation. In: Chemical Communications. 2012 ; Vol. 48, No. 48. pp. 6031-6033.
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