Absolute structure determination of chiral crystals consisting of achiral benzophenone with single-crystal X-ray Diffraction and its correlation with solid-state circular dichroism

Arimasa Matsumoto, Sumeru Tsuchiya, Yuki Hagiwara, Kazuhiko Ishikawa, Hideko Koshima, Toru Asahi, Kenso Soai

    Research output: Contribution to journalArticle

    Abstract

    Achiral benzophenone is one of the simplest organic aromatic ketones that crystallize in the chiral form. The absolute structure of chiral crystals consisting of achiral benzophenone was firstly determined with single-crystal X-ray diffraction analysis and the absolute structure was successfully correlated with the solid-state circular dichroism spectra.

    Original languageEnglish
    Pages (from-to)526-528
    Number of pages3
    JournalChemistry Letters
    Volume45
    Issue number5
    DOIs
    Publication statusPublished - 2016

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    Single crystals
    X ray diffraction
    Crystals
    Ketones
    X ray diffraction analysis
    benzophenone

    Keywords

    • Absolute structure
    • Benzophenone
    • Chiral crystallization

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Absolute structure determination of chiral crystals consisting of achiral benzophenone with single-crystal X-ray Diffraction and its correlation with solid-state circular dichroism. / Matsumoto, Arimasa; Tsuchiya, Sumeru; Hagiwara, Yuki; Ishikawa, Kazuhiko; Koshima, Hideko; Asahi, Toru; Soai, Kenso.

    In: Chemistry Letters, Vol. 45, No. 5, 2016, p. 526-528.

    Research output: Contribution to journalArticle

    Matsumoto, Arimasa ; Tsuchiya, Sumeru ; Hagiwara, Yuki ; Ishikawa, Kazuhiko ; Koshima, Hideko ; Asahi, Toru ; Soai, Kenso. / Absolute structure determination of chiral crystals consisting of achiral benzophenone with single-crystal X-ray Diffraction and its correlation with solid-state circular dichroism. In: Chemistry Letters. 2016 ; Vol. 45, No. 5. pp. 526-528.
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    AU - Koshima, Hideko

    AU - Asahi, Toru

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