Activation Volume as Evidence for a Dissociative-Interchange Mechanism of Nickel (II) Ion Complexation with Isoquinoline in Water, N,N-DimethyIformamide, Acetonitrile, Methanol, and Ethanol

Koji Ishihara; Shigenobu Funahashi; Motoharu Tanaka

doi:10.1021/ic00160a019

Activation Volume as Evidence for a Dissociative-Interchange Mechanism of Nickel (II) Ion Complexation with Isoquinoline in Water, N,N-DimethyIformamide, Acetonitrile, Methanol, and Ethanol

Koji Ishihara, Shigenobu Funahashi, Motoharu Tanaka

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Activation volumes for the complexation of nickel(II) ion with isoquinoline in various solvents were determined by a high-pressure stopped-flow technique. Values of activation volume for formation and dissociation of the (isoquinoline)nickel(II) complex are respectively 7.4 ± 1.3 and 8.9 ± 0.8 cm³ mol^-1 in water, 9.3 ± 0.3 and 12.2 ± 0.3 cm³ mol^-1 in N,N-di-methylformamide, 12.8 ± 0.6 and 9.9 ± 0.5 cm³ mol^-1 in methanol, and 12.6 ± 0.5 and 15.7 ± 1.1 cm³ mol^-1 in ethanol. The activation volume of the complex formation in acetonitrile is 9.4 ± 0.1 cm³ mol^-1. All the positive values of the activation volume strongly indicate that the ligand substitution reactions on nickel(II) ion proceed via a dissociative-interchange mechanism in these solvents.

Original language	English
Pages (from-to)	2564-2567
Number of pages	4
Journal	Inorganic Chemistry
Volume	22
Issue number	18
DOIs	https://doi.org/10.1021/ic00160a019
Publication status	Published - 1983 Aug
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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Activation Volume as Evidence for a Dissociative-Interchange Mechanism of Nickel (II) Ion Complexation with Isoquinoline in Water, N,N-DimethyIformamide, Acetonitrile, Methanol, and Ethanol. / Ishihara, Koji; Funahashi, Shigenobu; Tanaka, Motoharu.

In: Inorganic Chemistry, Vol. 22, No. 18, 08.1983, p. 2564-2567.

Research output: Contribution to journal › Article › peer-review

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abstract = "Activation volumes for the complexation of nickel(II) ion with isoquinoline in various solvents were determined by a high-pressure stopped-flow technique. Values of activation volume for formation and dissociation of the (isoquinoline)nickel(II) complex are respectively 7.4 ± 1.3 and 8.9 ± 0.8 cm3 mol-1 in water, 9.3 ± 0.3 and 12.2 ± 0.3 cm3 mol-1 in N,N-di-methylformamide, 12.8 ± 0.6 and 9.9 ± 0.5 cm3 mol-1 in methanol, and 12.6 ± 0.5 and 15.7 ± 1.1 cm3 mol-1 in ethanol. The activation volume of the complex formation in acetonitrile is 9.4 ± 0.1 cm3 mol-1. All the positive values of the activation volume strongly indicate that the ligand substitution reactions on nickel(II) ion proceed via a dissociative-interchange mechanism in these solvents.",

author = "Koji Ishihara and Shigenobu Funahashi and Motoharu Tanaka",

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T1 - Activation Volume as Evidence for a Dissociative-Interchange Mechanism of Nickel (II) Ion Complexation with Isoquinoline in Water, N,N-DimethyIformamide, Acetonitrile, Methanol, and Ethanol

AU - Ishihara, Koji

AU - Funahashi, Shigenobu

AU - Tanaka, Motoharu

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N2 - Activation volumes for the complexation of nickel(II) ion with isoquinoline in various solvents were determined by a high-pressure stopped-flow technique. Values of activation volume for formation and dissociation of the (isoquinoline)nickel(II) complex are respectively 7.4 ± 1.3 and 8.9 ± 0.8 cm3 mol-1 in water, 9.3 ± 0.3 and 12.2 ± 0.3 cm3 mol-1 in N,N-di-methylformamide, 12.8 ± 0.6 and 9.9 ± 0.5 cm3 mol-1 in methanol, and 12.6 ± 0.5 and 15.7 ± 1.1 cm3 mol-1 in ethanol. The activation volume of the complex formation in acetonitrile is 9.4 ± 0.1 cm3 mol-1. All the positive values of the activation volume strongly indicate that the ligand substitution reactions on nickel(II) ion proceed via a dissociative-interchange mechanism in these solvents.

AB - Activation volumes for the complexation of nickel(II) ion with isoquinoline in various solvents were determined by a high-pressure stopped-flow technique. Values of activation volume for formation and dissociation of the (isoquinoline)nickel(II) complex are respectively 7.4 ± 1.3 and 8.9 ± 0.8 cm3 mol-1 in water, 9.3 ± 0.3 and 12.2 ± 0.3 cm3 mol-1 in N,N-di-methylformamide, 12.8 ± 0.6 and 9.9 ± 0.5 cm3 mol-1 in methanol, and 12.6 ± 0.5 and 15.7 ± 1.1 cm3 mol-1 in ethanol. The activation volume of the complex formation in acetonitrile is 9.4 ± 0.1 cm3 mol-1. All the positive values of the activation volume strongly indicate that the ligand substitution reactions on nickel(II) ion proceed via a dissociative-interchange mechanism in these solvents.

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