Activation volume for the cobalt(II) ion complexation with N-methyltetraphenylporphine. Evidence for a dissociative interchange mechanism

Shigenobu Funahashi, Yushi Yamaguchi, Koji Ishihara, Motoharu Tanaka

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A positive activation volume (8.0 cm3 mol-1) for cobalt(II) ion incorporation into N-methyltetraphenylporphine in N,N-dimethylformamide, obtained by a high-pressure stopped-flow technique, is consistent with a dissociative interchange mechanism.

Original languageEnglish
Pages (from-to)976-977
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number17
Publication statusPublished - 1982
Externally publishedYes

Fingerprint

Dimethylformamide
Interchanges
Cobalt
Complexation
Chemical activation
Ions
Pressure
N-methyltetraphenylporphine

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Activation volume for the cobalt(II) ion complexation with N-methyltetraphenylporphine. Evidence for a dissociative interchange mechanism. / Funahashi, Shigenobu; Yamaguchi, Yushi; Ishihara, Koji; Tanaka, Motoharu.

In: Journal of the Chemical Society, Chemical Communications, No. 17, 1982, p. 976-977.

Research output: Contribution to journalArticle

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