Activity measurement of indium in liquid In-Sb-Ag and In-Sb-Te alloys by Emf method with zirconia solid electrolyte

S. Itabashi, Katsunori Yamaguchi, K. Kameda

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Emf of galvanic cells with zirconia solid electrolyte was measured to determine the activity of indium in the liquid In-Sb-Ag and In-Sb-Te systems in temperature ranges from 970 to 1280 K for the In-Sb-Ag system and for the In-Sb-Te from 870 to 1260 K. The following cells were used: Pt/Ni, NiO|ZrO2 (+ CaO) | In-Sb-Ag, In2O3/Re/Pt, Pt/Ni, NiO | ZrO2 (+ CaO) | In-Sb-Te, In2O3/Re/Pt. The isoactivity curves in the liquid In-Sb-Ag and In-Sb-Te systems at 1100 K were derived from combining the activity data of the In-Sb, In-Ag and In-Te binary alloys. The shape of isoactivity curves in the liquid In-Sb-Ag exhibits a slight bend to the Sb-Ag binary side, and those of the liquid In-Sb-Te gather from the whole composition range of the In-Sb binary alloy to the intermediate composition of the In-Te system.

Original languageEnglish
Pages (from-to)888-892
Number of pages5
JournalNippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals
Volume65
Issue number9
Publication statusPublished - 2001
Externally publishedYes

Fingerprint

Indium
Solid electrolytes
solid electrolytes
zirconium oxides
Zirconia
indium
Binary alloys
Liquids
Electric potential
binary alloys
liquids
electrolytic cells
curves
Chemical analysis
zirconium oxide
cells
Temperature
temperature

Keywords

  • Activity
  • Electromotive force
  • Indium-antimony-silver alloy
  • Indium-antimony-tellurium alloy
  • Solid electrolyte
  • Thermodynamics

ASJC Scopus subject areas

  • Metals and Alloys

Cite this

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title = "Activity measurement of indium in liquid In-Sb-Ag and In-Sb-Te alloys by Emf method with zirconia solid electrolyte",
abstract = "Emf of galvanic cells with zirconia solid electrolyte was measured to determine the activity of indium in the liquid In-Sb-Ag and In-Sb-Te systems in temperature ranges from 970 to 1280 K for the In-Sb-Ag system and for the In-Sb-Te from 870 to 1260 K. The following cells were used: Pt/Ni, NiO|ZrO2 (+ CaO) | In-Sb-Ag, In2O3/Re/Pt, Pt/Ni, NiO | ZrO2 (+ CaO) | In-Sb-Te, In2O3/Re/Pt. The isoactivity curves in the liquid In-Sb-Ag and In-Sb-Te systems at 1100 K were derived from combining the activity data of the In-Sb, In-Ag and In-Te binary alloys. The shape of isoactivity curves in the liquid In-Sb-Ag exhibits a slight bend to the Sb-Ag binary side, and those of the liquid In-Sb-Te gather from the whole composition range of the In-Sb binary alloy to the intermediate composition of the In-Te system.",
keywords = "Activity, Electromotive force, Indium-antimony-silver alloy, Indium-antimony-tellurium alloy, Solid electrolyte, Thermodynamics",
author = "S. Itabashi and Katsunori Yamaguchi and K. Kameda",
year = "2001",
language = "English",
volume = "65",
pages = "888--892",
journal = "Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals",
issn = "0021-4876",
publisher = "Japan Institute of Metals (JIM)",
number = "9",

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TY - JOUR

T1 - Activity measurement of indium in liquid In-Sb-Ag and In-Sb-Te alloys by Emf method with zirconia solid electrolyte

AU - Itabashi, S.

AU - Yamaguchi, Katsunori

AU - Kameda, K.

PY - 2001

Y1 - 2001

N2 - Emf of galvanic cells with zirconia solid electrolyte was measured to determine the activity of indium in the liquid In-Sb-Ag and In-Sb-Te systems in temperature ranges from 970 to 1280 K for the In-Sb-Ag system and for the In-Sb-Te from 870 to 1260 K. The following cells were used: Pt/Ni, NiO|ZrO2 (+ CaO) | In-Sb-Ag, In2O3/Re/Pt, Pt/Ni, NiO | ZrO2 (+ CaO) | In-Sb-Te, In2O3/Re/Pt. The isoactivity curves in the liquid In-Sb-Ag and In-Sb-Te systems at 1100 K were derived from combining the activity data of the In-Sb, In-Ag and In-Te binary alloys. The shape of isoactivity curves in the liquid In-Sb-Ag exhibits a slight bend to the Sb-Ag binary side, and those of the liquid In-Sb-Te gather from the whole composition range of the In-Sb binary alloy to the intermediate composition of the In-Te system.

AB - Emf of galvanic cells with zirconia solid electrolyte was measured to determine the activity of indium in the liquid In-Sb-Ag and In-Sb-Te systems in temperature ranges from 970 to 1280 K for the In-Sb-Ag system and for the In-Sb-Te from 870 to 1260 K. The following cells were used: Pt/Ni, NiO|ZrO2 (+ CaO) | In-Sb-Ag, In2O3/Re/Pt, Pt/Ni, NiO | ZrO2 (+ CaO) | In-Sb-Te, In2O3/Re/Pt. The isoactivity curves in the liquid In-Sb-Ag and In-Sb-Te systems at 1100 K were derived from combining the activity data of the In-Sb, In-Ag and In-Te binary alloys. The shape of isoactivity curves in the liquid In-Sb-Ag exhibits a slight bend to the Sb-Ag binary side, and those of the liquid In-Sb-Te gather from the whole composition range of the In-Sb binary alloy to the intermediate composition of the In-Te system.

KW - Activity

KW - Electromotive force

KW - Indium-antimony-silver alloy

KW - Indium-antimony-tellurium alloy

KW - Solid electrolyte

KW - Thermodynamics

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M3 - Article

VL - 65

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EP - 892

JO - Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals

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SN - 0021-4876

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