Adsorption and aggregation of a cationic cyanine dye on layered clay minerals

Nobuyoshi Miyamoto, Ryo Kawai, Kazuyuki Kuroda, Makoto Ogawa

Research output: Contribution to journalArticle

88 Citations (Scopus)

Abstract

The adsorption and aggregation of a cationic cyanine dye, 1,1'-diethyl-2,2'-cyanine (pseudoisocyanine; abbreviated as PIC), on various clays have been investigated. The PIC formed J-aggregates on Na-montmorillonite and synthetic Na-fluor-tetrasilicic mica (TSM), while they distributed molecularly on synthetic Na-saponite and synthetic Na-hectorites. The particle size of the clays was considered to be a dominant factor to control the aggregation of PIC. The J-aggregate formation was suppressed when tetramethylammonium-montmorillonite was employed as a host material. Ethylene glycol in the suspension was also responsible for the suppression of J-aggregate formation of PIC. Thus, the aggregation of PIC was effectively controlled by the species surrounding the PIC cations as well as the nature of clays. (C) 2000 Elsevier Science B.V. All rights reserved.

Original languageEnglish
Pages (from-to)161-170
Number of pages10
JournalApplied Clay Science
Volume16
Issue number3-4
DOIs
Publication statusPublished - 2000 Mar 1

Keywords

  • Clay minerals
  • Cyanine dye
  • Ethylene glycol
  • J-aggregate
  • Tetramethylammonium

ASJC Scopus subject areas

  • Geology
  • Geochemistry and Petrology

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