Abstract
NaX zeolite is used to collect and decompose chlorofluorocarbons (CFCs) and to determine the behavior of CFC-11 molecules in zeolitic pores using various methods. At room temperature, CFC-11 molecules are adsorbed on the micropores of NaX zeolite, and at 400°C CFC-11 molecules were decomposed by the catalytic reaction of NaX zeolite. Approximately 30 CFC-11 molecules are adsorbed and 90 CFC-11 molecules are decomposed per unit cell of NaX zeolite. HCl and HF gases are detected in the outlet gas of the decomposed CFC-11. The results indicate that Al-O bonds in the zeolite crystal structure are destroyed. The destruction of the zeolite crystal structure tends to occur on the selective planes along the hhh, hh0 and 3hhh directions.
| Original language | English |
|---|---|
| Pages (from-to) | 264-267 |
| Number of pages | 4 |
| Journal | Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan |
| Volume | 104 |
| Issue number | 4 |
| Publication status | Published - 1996 |
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Keywords
- Adsorption
- Chlorofluorocarbons (CFCs)
- Decomposition
- NaX zeolite
ASJC Scopus subject areas
- Ceramics and Composites
Cite this
Adsorption and catalytic reaction of CFC-11 on NaX zeolite. / Hiraiwa, Mana Yasui; Yamazaki, Atsushi; Nagoya, Toshio.
In: Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan, Vol. 104, No. 4, 1996, p. 264-267.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Adsorption and catalytic reaction of CFC-11 on NaX zeolite
AU - Hiraiwa, Mana Yasui
AU - Yamazaki, Atsushi
AU - Nagoya, Toshio
PY - 1996
Y1 - 1996
N2 - NaX zeolite is used to collect and decompose chlorofluorocarbons (CFCs) and to determine the behavior of CFC-11 molecules in zeolitic pores using various methods. At room temperature, CFC-11 molecules are adsorbed on the micropores of NaX zeolite, and at 400°C CFC-11 molecules were decomposed by the catalytic reaction of NaX zeolite. Approximately 30 CFC-11 molecules are adsorbed and 90 CFC-11 molecules are decomposed per unit cell of NaX zeolite. HCl and HF gases are detected in the outlet gas of the decomposed CFC-11. The results indicate that Al-O bonds in the zeolite crystal structure are destroyed. The destruction of the zeolite crystal structure tends to occur on the selective planes along the hhh, hh0 and 3hhh directions.
AB - NaX zeolite is used to collect and decompose chlorofluorocarbons (CFCs) and to determine the behavior of CFC-11 molecules in zeolitic pores using various methods. At room temperature, CFC-11 molecules are adsorbed on the micropores of NaX zeolite, and at 400°C CFC-11 molecules were decomposed by the catalytic reaction of NaX zeolite. Approximately 30 CFC-11 molecules are adsorbed and 90 CFC-11 molecules are decomposed per unit cell of NaX zeolite. HCl and HF gases are detected in the outlet gas of the decomposed CFC-11. The results indicate that Al-O bonds in the zeolite crystal structure are destroyed. The destruction of the zeolite crystal structure tends to occur on the selective planes along the hhh, hh0 and 3hhh directions.
KW - Adsorption
KW - Chlorofluorocarbons (CFCs)
KW - Decomposition
KW - NaX zeolite
UR - http://www.scopus.com/inward/record.url?scp=0030124449&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0030124449&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0030124449
VL - 104
SP - 264
EP - 267
JO - Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan
JF - Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan
SN - 1882-0743
IS - 4
ER -