Adsorption of a cationic porphyrin onto mesoporous silicas

Atsuko Yoshida, Norishige Kakegawa, Makoto Ogawa

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

The adsorption of a cationic porphyrin, tetrakis-(N-methyl-4-pyridiniumyl)porphine, into mesoporous silicas from solution of tetrakis-(N-methyl-4-pyridiniumyl)porphine p-toluene sulfonate was investigated. Irrespective of the pore size (2.4, 3.5 and 4.2 nm), the cationic porphyrin was adsorbed effectively onto mesoporous silicas to give brown-colored powders. Depending on the amounts adsorbed, which correlate with the average intermolecular distance, the porphines tend to aggregate (dimer).

Original languageEnglish
Pages (from-to)721-731
Number of pages11
JournalResearch on Chemical Intermediates
Volume29
Issue number7-9
DOIs
Publication statusPublished - 2003

Fingerprint

Porphyrins
Silicon Dioxide
Adsorption
Dimers
Powders
Pore size
porphine
4-toluenesulfonic acid

Keywords

  • Adsorption
  • Aggregation
  • Luminescence
  • Mesoporous silica
  • Porphyrin

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Adsorption of a cationic porphyrin onto mesoporous silicas. / Yoshida, Atsuko; Kakegawa, Norishige; Ogawa, Makoto.

In: Research on Chemical Intermediates, Vol. 29, No. 7-9, 2003, p. 721-731.

Research output: Contribution to journalArticle

Yoshida, Atsuko ; Kakegawa, Norishige ; Ogawa, Makoto. / Adsorption of a cationic porphyrin onto mesoporous silicas. In: Research on Chemical Intermediates. 2003 ; Vol. 29, No. 7-9. pp. 721-731.
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