Alkyl chain length effect on growth kinetics of n-alkanethiol self-assembled monolayers on gold studied by x-ray photoelectron spectroscopy

Takao Ishida, Naoki Nishida, Satoshi Tsuneda, Masahiko Hara, Hiroyuki Sasabe, Wolfgang Knoll

Research output: Contribution to journalArticle

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Abstract

Growth kinetics of self-assembled monolayers (SAMs) of n-alkanethiols on gold substrates was studied by X-ray photoelectron spectroscopy (XPS). We compared adsorption kinetics for three alkanethiol homologues: butanethiol (C4SH), dodecanethiol (C12SH), and octadecanethiol (C18SH). Results of quantitative analysis by XPS suggested that the adsorption rate of short alkyl chain thiols is higher than that of long ones on gold substrates at the initial growth stage, in contrast to previous reports. For C4SH SAM formation, we have also confirmed the occurrence of a replacement effect from contamination to SAM on gold, based on our observation of a decrease in the amount of carbon and an increase in the amount of gold where as determined from XPS spectra.

Original languageEnglish
JournalJapanese Journal of Applied Physics, Part 2: Letters
Volume35
Issue number12 B
Publication statusPublished - 1996
Externally publishedYes

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Growth kinetics
Self assembled monolayers
Photoelectron spectroscopy
Chain length
x ray spectroscopy
Gold
photoelectron spectroscopy
gold
X rays
X ray photoelectron spectroscopy
kinetics
Adsorption
adsorption
x rays
Substrates
thiols
quantitative analysis
contamination
Contamination
occurrences

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)

Cite this

Alkyl chain length effect on growth kinetics of n-alkanethiol self-assembled monolayers on gold studied by x-ray photoelectron spectroscopy. / Ishida, Takao; Nishida, Naoki; Tsuneda, Satoshi; Hara, Masahiko; Sasabe, Hiroyuki; Knoll, Wolfgang.

In: Japanese Journal of Applied Physics, Part 2: Letters, Vol. 35, No. 12 B, 1996.

Research output: Contribution to journalArticle

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AU - Hara, Masahiko

AU - Sasabe, Hiroyuki

AU - Knoll, Wolfgang

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