Alkylation of isobutane by 1-butene over H-beta zeolite in CSTR (Part 2) deactivation mechanism of zeolite catalyst and optimization of CSTR conditions

Yasushi Sekine, Yu Ichi Tajima, Yo Suke Ichikawa, Masahiko Matsukata, Eiichi Kikuchi

    Research output: Contribution to journalArticle

    2 Citations (Scopus)

    Abstract

    DGC-H-beta zeolite catalyst has higher activity and selectivity for the alkylation of isobutane with 1-butene in a CSTR. The cause of the deactivation of the catalyst and the optimum reaction conditions were investigated. Deactivation of the catalyst was caused not by adsorbed carbon species but by hydrocarbons formed by multiple alkylation or oligomerization of olefin. Optimized conditions to avoid these reactions achieved stable selective alkylation.

    Original languageEnglish
    Pages (from-to)308-318
    Number of pages11
    JournalJournal of the Japan Petroleum Institute
    Volume55
    Issue number5
    DOIs
    Publication statusPublished - 2012

      Fingerprint

    Keywords

    • Beta zeolite
    • Continuously stirred tank reactor
    • Deactivation
    • Isobutane alkylation

    ASJC Scopus subject areas

    • Energy Engineering and Power Technology
    • Fuel Technology

    Cite this