Allylic carbonates. Efficient allylating agents of carbonucleophiles in palladium-catalyzed reactions under neutral conditions

Jiro Tsuji*, Isao Shimizu, Ichiro Minami, Yukihiro Ohashi, Teruo Sugiura, Kazuhiko Takahashi

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    243 Citations (Scopus)

    Abstract

    Allylation of β-keto esters or malonates was carried out in good yields under neutral conditions by using allylic carbonates in the presence of palladium-phosphine catalyst. Although simple ketones, esters, nitriles, and sulfones hardly react with allylic carbonates, α-alkenyl or α-aryl ketones, esters, nitriles, and sulfones were also allylated by using palladium-bis(diphenylphosphino)ethane catalyst under neutral conditions.

    Original languageEnglish
    Pages (from-to)1523-1529
    Number of pages7
    JournalJournal of Organic Chemistry
    Volume50
    Issue number9
    Publication statusPublished - 1985

    ASJC Scopus subject areas

    • Organic Chemistry

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