Amine Enrichment of Thin-Film Composite Membranes via Low Pressure Plasma Polymerization for Antimicrobial Adhesion

Rackel Reis, Ludovic F. Dumée, Li He, Fenghua She, John D. Orbell, Bjorn Winther Jensen, Mikel C. Duke

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Thin-film composite membranes, primarily based on poly(amide) (PA) semipermeable materials, are nowadays the dominant technology used in pressure driven water desalination systems. Despite offering superior water permeation and salt selectivity, their surface properties, such as their charge and roughness, cannot be extensively tuned due to the intrinsic fabrication process of the membranes by interfacial polymerization. The alteration of these properties would lead to a better control of the materials surface zeta potential, which is critical to finely tune selectivity and enhance the membrane materials stability when exposed to complex industrial waste streams. Low pressure plasma was employed to introduce amine functionalities onto the PA surface of commercially available thin-film composite (TFC) membranes. Morphological changes after plasma polymerization were analyzed by SEM and AFM, and average surface roughness decreased by 29%. Amine enrichment provided isoelectric point changes from pH 3.7 to 5.2 for 5 to 15 min of plasma polymerization time. Synchrotron FTIR mappings of the amine-modified surface indicated the addition of a discrete 60 nm film to the PA layer. Furthermore, metal affinity was confirmed by the enhanced binding of silver to the modified surface, supported by an increased antimicrobial functionality with demonstrable elimination of E. coli growth. Essential salt rejection was shown minimally compromised for faster polymerization processes. Plasma polymerization is therefore a viable route to producing functional amine enriched thin-film composite PA membrane surfaces.

Original languageEnglish
Pages (from-to)14644-14653
Number of pages10
JournalACS Applied Materials and Interfaces
Volume7
Issue number27
DOIs
Publication statusPublished - 2015 Jul 15
Externally publishedYes

Fingerprint

Plasma polymerization
Composite membranes
Polymerization
Amines
Adhesion
Pressure
Thin films
Membranes
Salts
Surface roughness
Industrial Waste
Synchrotrons
Surface Properties
Water
Industrial wastes
Isoelectric Point
Fourier Transform Infrared Spectroscopy
Zeta potential
Desalination
Amides

Keywords

  • amine enrichment
  • antimicrobial properties
  • functional thin-film coatings
  • nanoscale surface engineering
  • plasma polymerization

ASJC Scopus subject areas

  • Materials Science(all)
  • Medicine(all)

Cite this

Amine Enrichment of Thin-Film Composite Membranes via Low Pressure Plasma Polymerization for Antimicrobial Adhesion. / Reis, Rackel; Dumée, Ludovic F.; He, Li; She, Fenghua; Orbell, John D.; Winther Jensen, Bjorn; Duke, Mikel C.

In: ACS Applied Materials and Interfaces, Vol. 7, No. 27, 15.07.2015, p. 14644-14653.

Research output: Contribution to journalArticle

Reis, Rackel ; Dumée, Ludovic F. ; He, Li ; She, Fenghua ; Orbell, John D. ; Winther Jensen, Bjorn ; Duke, Mikel C. / Amine Enrichment of Thin-Film Composite Membranes via Low Pressure Plasma Polymerization for Antimicrobial Adhesion. In: ACS Applied Materials and Interfaces. 2015 ; Vol. 7, No. 27. pp. 14644-14653.
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