An Electron Diffraction Study on Mixed PdCI2/SnCI2 Catalysts for Electroless Plating

Tetsuya Osaka, Hideaki Nagasaka, Fumio Goto

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

The activated or catalyzed surface conditions for initiating electroless metal deposition were studied by means of transmission electron microscopy and electron diffraction analysis. Four mixed PdCI2/SnCI2 catalysts, including two commercial samples, and five accelerators (NaOH, HC1, H2SO4, NH4OH, and NH4BF4) were used in this study. The acceleration with NaOH gave the finest remaining particles which were almost bare active nuclei, while the acceleration with ammonate group (NH4OH and NH4BF4) coagulated small particles to produce high density particles. The electron diffraction patterns after activation, for the catalysts prepared in our laboratory, showed amorphous broad diffraction rings which were explained as fee structure, while for the commercial catalysts, they showed relatively sharp and netlike profiles which could be attributed to orthorhombic structure. The electron diffraction patterns after acceleration with NaOH became the sharper profiles of fee structure, however in the case of ammonate group, they showed the complicated profiles of non-fee structure. Finally the catalytically active sites or nuclei are discussed.

Original languageEnglish
Pages (from-to)2343-2346
Number of pages4
JournalJournal of the Electrochemical Society
Volume127
Issue number11
DOIs
Publication statusPublished - 1980 Nov

Keywords

  • electroless plating
  • mixed PdCk/SnCI2 catalyst

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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