An inorganic-organic hybrid possessing a two-dimensional Ti-O network and surface ethoxy groups prepared via a reaction of titanium oxychloride with lithium ethoxide

Natsuki Watanabe, Yoshitaka Kamochi, Seiichi Tahara, Nobuhiro Kumada, Yoshiyuki Sugahara

    Research output: Contribution to journalArticle

    3 Citations (Scopus)

    Abstract

    A new layered inorganic-organic hybrid possessing a Ti-O network has been prepared by a reaction between titanium oxychloride (TiOCl) and lithium ethoxide (LiOEt) at 120 °C for 7 days. The XRD analysis indicates that the interlayer distance of TiOCl increases from 0.80 to 1.19nm, and the solid-state 13CNMR spectroscopy and elemental analysis show partial substitution of ethoxy groups for chlorine atoms.

    Original languageEnglish
    Pages (from-to)244-245
    Number of pages2
    JournalChemistry Letters
    Volume38
    Issue number3
    DOIs
    Publication statusPublished - 2009

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    Titanium
    Lithium
    Chlorine
    Substitution reactions
    Spectroscopy
    Atoms
    Chemical analysis

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    An inorganic-organic hybrid possessing a two-dimensional Ti-O network and surface ethoxy groups prepared via a reaction of titanium oxychloride with lithium ethoxide. / Watanabe, Natsuki; Kamochi, Yoshitaka; Tahara, Seiichi; Kumada, Nobuhiro; Sugahara, Yoshiyuki.

    In: Chemistry Letters, Vol. 38, No. 3, 2009, p. 244-245.

    Research output: Contribution to journalArticle

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    AU - Kamochi, Yoshitaka

    AU - Tahara, Seiichi

    AU - Kumada, Nobuhiro

    AU - Sugahara, Yoshiyuki

    PY - 2009

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