An Ultrahigh Output Rechargeable Electrode of a Hydrophilic Radical Polymer/Nanocarbon Hybrid with an Exceptionally Large Current Density beyond 1 A cm-2

Kan Hatakeyama, Hisato Wakamatsu, Ryu Katagiri, Kenichi Oyaizu, Hiroyuki Nishide

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Facile charge transport by a hydrophilic organic radical-substituted polymer and the 3D current collection by a self-assembled mesh of single-walled carbon nanotube bundles lead to the operation of an ultrahigh-output rechargeable electrode. Exceptionally large current density beyond 1 A cm-2 and high areal capacity around 3 mAh cm-2 are achieved, which are 101-2 times larger than those of the previously reported so-called "ultrafast electrodes." A sub-millimeter-thick, flexible, highly safe organic redox polymer-based rechargeable device with an aqueous sodium chloride electrolyte is fabricated to demonstrate the superior performance.

Original languageEnglish
JournalAdvanced Materials
DOIs
Publication statusAccepted/In press - 2018 Jan 1

Fingerprint

Polymers
Current density
Electrodes
Single-walled carbon nanotubes (SWCN)
Sodium chloride
Sodium Chloride
Electrolytes
Charge transfer
Oxidation-Reduction

Keywords

  • Electrode-active materials
  • Radical molecules
  • Rechargeable devices
  • Redox polymers
  • Single-walled carbon nanotube

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

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abstract = "Facile charge transport by a hydrophilic organic radical-substituted polymer and the 3D current collection by a self-assembled mesh of single-walled carbon nanotube bundles lead to the operation of an ultrahigh-output rechargeable electrode. Exceptionally large current density beyond 1 A cm-2 and high areal capacity around 3 mAh cm-2 are achieved, which are 101-2 times larger than those of the previously reported so-called {"}ultrafast electrodes.{"} A sub-millimeter-thick, flexible, highly safe organic redox polymer-based rechargeable device with an aqueous sodium chloride electrolyte is fabricated to demonstrate the superior performance.",
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AU - Wakamatsu, Hisato

AU - Katagiri, Ryu

AU - Oyaizu, Kenichi

AU - Nishide, Hiroyuki

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AB - Facile charge transport by a hydrophilic organic radical-substituted polymer and the 3D current collection by a self-assembled mesh of single-walled carbon nanotube bundles lead to the operation of an ultrahigh-output rechargeable electrode. Exceptionally large current density beyond 1 A cm-2 and high areal capacity around 3 mAh cm-2 are achieved, which are 101-2 times larger than those of the previously reported so-called "ultrafast electrodes." A sub-millimeter-thick, flexible, highly safe organic redox polymer-based rechargeable device with an aqueous sodium chloride electrolyte is fabricated to demonstrate the superior performance.

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