An unbridged platinum(III) dimer with added chloro ligands in equatorial sites, [Pt2Cl2(phpy)4] (Hphpy = phenylpyridine), synthesized by an oxidation with aurous complex

Tadashi Yamaguchi, Osamu Kubota, Tasuku Ito

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19 Citations (Scopus)

Abstract

An unsupported platinum(III) dimer having added chloro ligands at equatorial sites and novel axial-equatorial chelate ligands, [Pt 2Cl2(phpy)4] (Hphpy = phenylpyridine) was obtained from an oxidative addition reaction of [Pt(phpy)2] with [AuCl(SMe2)].

Original languageEnglish
Pages (from-to)190-191
Number of pages2
JournalChemistry Letters
Volume33
Issue number2
DOIs
Publication statusPublished - 2004 Feb 5
Externally publishedYes

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Platinum
Dimers
Ligands
Oxidation
Addition reactions
4-phenylpyridine

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "An unbridged platinum(III) dimer with added chloro ligands in equatorial sites, [Pt2Cl2(phpy)4] (Hphpy = phenylpyridine), synthesized by an oxidation with aurous complex",
abstract = "An unsupported platinum(III) dimer having added chloro ligands at equatorial sites and novel axial-equatorial chelate ligands, [Pt 2Cl2(phpy)4] (Hphpy = phenylpyridine) was obtained from an oxidative addition reaction of [Pt(phpy)2] with [AuCl(SMe2)].",
author = "Tadashi Yamaguchi and Osamu Kubota and Tasuku Ito",
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AU - Kubota, Osamu

AU - Ito, Tasuku

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N2 - An unsupported platinum(III) dimer having added chloro ligands at equatorial sites and novel axial-equatorial chelate ligands, [Pt 2Cl2(phpy)4] (Hphpy = phenylpyridine) was obtained from an oxidative addition reaction of [Pt(phpy)2] with [AuCl(SMe2)].

AB - An unsupported platinum(III) dimer having added chloro ligands at equatorial sites and novel axial-equatorial chelate ligands, [Pt 2Cl2(phpy)4] (Hphpy = phenylpyridine) was obtained from an oxidative addition reaction of [Pt(phpy)2] with [AuCl(SMe2)].

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