Analysis of catalytic activity of novel cathode catalyst for fuel cells using polymer-cobalt complexes

Kenichi Oyaizu, Koji Ikkanda, Mizuki Kitao, Ken Tanaka, Aritomo Yamaguchi, Makoto Yuasa

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Oxidative polymerization of pyrrole onto a surface of a carbon particle dispersed in an electrolyte solution was performed using a fluid-bed electrode where the carbon particle served as a working electrode. Complexation of the polypyrrole (PPy)-modified carbon particle with a cobalt ion by a heterogeneous process proceeded irreversibly and almost quantitatively to give a Co-PPy complex-modified carbon particle, which proved to be a good catalyst for the electro-reduction of oxygen. Voltammetric analysis using an electrode modified with a Nafion film containing the catalyst revealed that oxygen was reduced by four electrons at a high peak potential. Heat treatment of the catalyst greatly improved the catalytic activity. The improvement in the activity was ascribed to the decrease in the size of the active site, which led to a closer packing of the catalyst at the carbon surface. The high activity and the stability suggested that the catalyst can be used as an alternative to the conventional Pt/C catalyst in fuel cells. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

Original languageEnglish
Title of host publicationACS National Meeting Book of Abstracts
Volume229
Edition1
Publication statusPublished - 2005
Externally publishedYes
Event229th ACS National Meeting - San Diego, CA., United States
Duration: 2005 Mar 132005 Mar 17

Other

Other229th ACS National Meeting
CountryUnited States
CitySan Diego, CA.
Period05/3/1305/3/17

Fingerprint

Cobalt
Fuel cells
Catalyst activity
Polymers
Cathodes
Carbon
Catalysts
Electrodes
Oxygen
Pyrroles
Complexation
Electrolytes
Heat treatment
Polymerization
Ions
Fluids
Electrons

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Oyaizu, K., Ikkanda, K., Kitao, M., Tanaka, K., Yamaguchi, A., & Yuasa, M. (2005). Analysis of catalytic activity of novel cathode catalyst for fuel cells using polymer-cobalt complexes. In ACS National Meeting Book of Abstracts (1 ed., Vol. 229)

Analysis of catalytic activity of novel cathode catalyst for fuel cells using polymer-cobalt complexes. / Oyaizu, Kenichi; Ikkanda, Koji; Kitao, Mizuki; Tanaka, Ken; Yamaguchi, Aritomo; Yuasa, Makoto.

ACS National Meeting Book of Abstracts. Vol. 229 1. ed. 2005.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Oyaizu, K, Ikkanda, K, Kitao, M, Tanaka, K, Yamaguchi, A & Yuasa, M 2005, Analysis of catalytic activity of novel cathode catalyst for fuel cells using polymer-cobalt complexes. in ACS National Meeting Book of Abstracts. 1 edn, vol. 229, 229th ACS National Meeting, San Diego, CA., United States, 05/3/13.
Oyaizu K, Ikkanda K, Kitao M, Tanaka K, Yamaguchi A, Yuasa M. Analysis of catalytic activity of novel cathode catalyst for fuel cells using polymer-cobalt complexes. In ACS National Meeting Book of Abstracts. 1 ed. Vol. 229. 2005
Oyaizu, Kenichi ; Ikkanda, Koji ; Kitao, Mizuki ; Tanaka, Ken ; Yamaguchi, Aritomo ; Yuasa, Makoto. / Analysis of catalytic activity of novel cathode catalyst for fuel cells using polymer-cobalt complexes. ACS National Meeting Book of Abstracts. Vol. 229 1. ed. 2005.
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