Analysis of self-assembly: Porphyrins with uracil and melamine derivatives

Satoshi Arai, Daisuke Niwa, Shinji Takeoka, Hiroyuki Nishide

Research output: Contribution to conferencePaperpeer-review

Abstract

Porphyrin derivatives UP1 were synthesized by condensation with N-pentyl orotic acid and bis(diaminophenyl) porphyrin derivative by using BOP reagent. The mixed benzene solution with Glu-M and UP1 was heated at 50°C to obtain a transparent solution. The solution was gelated after standing for 1 hr at room temperature. The benzene casted film of UP1 and Glu-M showed anisotropy, whereas UP1 without Glu-M showed isotropy. However, the anisotropy disappeared after heating at 90°C, which revealed lyotropic LC phase.

Original languageEnglish
Number of pages1
Publication statusPublished - 2005 Dec 1
Event54th SPSJ Annual Meeting 2005 - Yokohama, Japan
Duration: 2005 May 252005 May 27

Conference

Conference54th SPSJ Annual Meeting 2005
CountryJapan
CityYokohama
Period05/5/2505/5/27

Keywords

  • Atrop isomer
  • Hydrogen bond
  • Porphyrin
  • Self-assembly

ASJC Scopus subject areas

  • Engineering(all)

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