Analysis of unstable two-phase region in wurtzite group III nitride ternary alloy using modified valence force field model

Toru Takayama, Masaaki Yuri, Kunio Itoh, Takaaki Baba, James S. Harris

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18 Citations (Scopus)

Abstract

The III-nitride ternary system is studied with unstable two-phase region in the phase field. The unstable two-phase region is analyzed using a strictly regular solution model. The interaction parameter used in the analysis is obtained from a strain energy calculation using the valence force field model, modified for both wurtzite and zinc-blende structures to avoid overestimation of the strain energy. The structural deviation from an ideal wurtzite structure in InN, GaN, and AlN is also taken into account in our model. According to the calculated results of the interaction parameters, the critical temperature for wurtzite InGaN, InAlN, and GaAlN are found to be 1967 K, 3399 K, and 181 K, respectively. This suggests that, at a typical growth temperature of 800-1000 °C a wide unstable two-phase region exists in both InGaN and InAlN. In order to show the validity of our calculation results, we compare the calculated results and the experimental results using the calculation of the interaction parameter for the InGaAs system. The calculated results agree well with the experimental results.

Original languageEnglish
Pages (from-to)5057-5062
Number of pages6
JournalJapanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
Volume39
Issue number9 A
Publication statusPublished - 2000 Sep
Externally publishedYes

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Ternary alloys
ternary alloys
Nitrides
wurtzite
field theory (physics)
nitrides
Strain energy
valence
interactions
Growth temperature
Ternary systems
ternary systems
critical temperature
Zinc
zinc
deviation
energy
Temperature
temperature

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)

Cite this

Analysis of unstable two-phase region in wurtzite group III nitride ternary alloy using modified valence force field model. / Takayama, Toru; Yuri, Masaaki; Itoh, Kunio; Baba, Takaaki; Harris, James S.

In: Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, Vol. 39, No. 9 A, 09.2000, p. 5057-5062.

Research output: Contribution to journalArticle

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