Anion Doping-undoping Process of Electrochemically Polymerized

Polypyrrole Film, Yuji Yatsuda, Hiroshi Sakai, Tetsuya Osaka

Research output: Contribution to journalArticle

Abstract

The electrochemical anion doping-undoping of the film, (C4H3N)x, prepared by the electrochemical polymerization of pyrrole was investigated under potentiostatic conditions. The impedance behavior of the doping-undoping process into the C4H3N)x film was measured by the FFT method and it was represented by the Randles-type equivalent circuit. The resistive Rr value sensitively reflected the variation of doping-undoping process of the C4H3N)x film in a similar, manner as in the case of a polyacetylene film, suggesting that the dopant diffusion process into the polypyrrole film controled the doping process. A charging-discharging of simple Li-C4H3N)x battery in propylene carbonate was also investigated. The resistive Rr value of the cell clearly had the correlation with open-circuit voltage and the charged conditions.

Original languageEnglish
Pages (from-to)1331-1336
Number of pages6
JournalNippon Kagaku Kaishi
Volume1985
Issue number7
DOIs
Publication statusPublished - 1985

Fingerprint

Anions
Negative ions
Doping (additives)
Polyacetylenes
Pyrroles
Electropolymerization
Polypyrroles
Open circuit voltage
Equivalent circuits
Fast Fourier transforms
Propylene
Carbonates

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Anion Doping-undoping Process of Electrochemically Polymerized. / Film, Polypyrrole; Yatsuda, Yuji; Sakai, Hiroshi; Osaka, Tetsuya.

In: Nippon Kagaku Kaishi, Vol. 1985, No. 7, 1985, p. 1331-1336.

Research output: Contribution to journalArticle

Film, Polypyrrole ; Yatsuda, Yuji ; Sakai, Hiroshi ; Osaka, Tetsuya. / Anion Doping-undoping Process of Electrochemically Polymerized. In: Nippon Kagaku Kaishi. 1985 ; Vol. 1985, No. 7. pp. 1331-1336.
@article{b912bc88045544d6b733d70cd0da7c6e,
title = "Anion Doping-undoping Process of Electrochemically Polymerized",
abstract = "The electrochemical anion doping-undoping of the film, (C4H3N)x, prepared by the electrochemical polymerization of pyrrole was investigated under potentiostatic conditions. The impedance behavior of the doping-undoping process into the C4H3N)x film was measured by the FFT method and it was represented by the Randles-type equivalent circuit. The resistive Rr value sensitively reflected the variation of doping-undoping process of the C4H3N)x film in a similar, manner as in the case of a polyacetylene film, suggesting that the dopant diffusion process into the polypyrrole film controled the doping process. A charging-discharging of simple Li-C4H3N)x battery in propylene carbonate was also investigated. The resistive Rr value of the cell clearly had the correlation with open-circuit voltage and the charged conditions.",
author = "Polypyrrole Film and Yuji Yatsuda and Hiroshi Sakai and Tetsuya Osaka",
year = "1985",
doi = "10.1246/nikkashi.1985.1331",
language = "English",
volume = "1985",
pages = "1331--1336",
journal = "Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal",
issn = "0369-4577",
publisher = "Chemical Society of Japan",
number = "7",

}

TY - JOUR

T1 - Anion Doping-undoping Process of Electrochemically Polymerized

AU - Film, Polypyrrole

AU - Yatsuda, Yuji

AU - Sakai, Hiroshi

AU - Osaka, Tetsuya

PY - 1985

Y1 - 1985

N2 - The electrochemical anion doping-undoping of the film, (C4H3N)x, prepared by the electrochemical polymerization of pyrrole was investigated under potentiostatic conditions. The impedance behavior of the doping-undoping process into the C4H3N)x film was measured by the FFT method and it was represented by the Randles-type equivalent circuit. The resistive Rr value sensitively reflected the variation of doping-undoping process of the C4H3N)x film in a similar, manner as in the case of a polyacetylene film, suggesting that the dopant diffusion process into the polypyrrole film controled the doping process. A charging-discharging of simple Li-C4H3N)x battery in propylene carbonate was also investigated. The resistive Rr value of the cell clearly had the correlation with open-circuit voltage and the charged conditions.

AB - The electrochemical anion doping-undoping of the film, (C4H3N)x, prepared by the electrochemical polymerization of pyrrole was investigated under potentiostatic conditions. The impedance behavior of the doping-undoping process into the C4H3N)x film was measured by the FFT method and it was represented by the Randles-type equivalent circuit. The resistive Rr value sensitively reflected the variation of doping-undoping process of the C4H3N)x film in a similar, manner as in the case of a polyacetylene film, suggesting that the dopant diffusion process into the polypyrrole film controled the doping process. A charging-discharging of simple Li-C4H3N)x battery in propylene carbonate was also investigated. The resistive Rr value of the cell clearly had the correlation with open-circuit voltage and the charged conditions.

UR - http://www.scopus.com/inward/record.url?scp=85016521837&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85016521837&partnerID=8YFLogxK

U2 - 10.1246/nikkashi.1985.1331

DO - 10.1246/nikkashi.1985.1331

M3 - Article

AN - SCOPUS:85016521837

VL - 1985

SP - 1331

EP - 1336

JO - Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal

JF - Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal

SN - 0369-4577

IS - 7

ER -