Anionic iron complexes with a bond between an ate-type pentacoordinated germanium and an iron atom

Naokazu Kano; Naohito Yoshinari; Yusuke Shibata; Mariko Miyachi; Takayuki Kawashima; Masaya Enomoto; Atsushi Okazawa; Norimichi Kojima; Jing Dong Guo; Shigeru Nagase

doi:10.1021/om300915y

Anionic iron complexes with a bond between an ate-type pentacoordinated germanium and an iron atom

Naokazu Kano^*, Naohito Yoshinari, Yusuke Shibata, Mariko Miyachi, Takayuki Kawashima, Masaya Enomoto, Atsushi Okazawa, Norimichi Kojima, Jing Dong Guo, Shigeru Nagase

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The first stable anionic iron(0) complexes bearing an ate-type pentacoordinated germanium(IV) ligand were synthesized. The X-ray crystallographic analysis shows trigonal-bipyramidal and piano-stool geometries of germanium and iron, respectively. The complexes have moderately electron-rich iron centers and polar Ge-Fe bonds which can be cleaved by oxidation.

Original language	English
Pages (from-to)	8059-8062
Number of pages	4
Journal	Organometallics
Volume	31
Issue number	23
DOIs	https://doi.org/10.1021/om300915y
Publication status	Published - 2012 Dec 10
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "The first stable anionic iron(0) complexes bearing an ate-type pentacoordinated germanium(IV) ligand were synthesized. The X-ray crystallographic analysis shows trigonal-bipyramidal and piano-stool geometries of germanium and iron, respectively. The complexes have moderately electron-rich iron centers and polar Ge-Fe bonds which can be cleaved by oxidation.",

author = "Naokazu Kano and Naohito Yoshinari and Yusuke Shibata and Mariko Miyachi and Takayuki Kawashima and Masaya Enomoto and Atsushi Okazawa and Norimichi Kojima and Guo, {Jing Dong} and Shigeru Nagase",

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language = "English",

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T1 - Anionic iron complexes with a bond between an ate-type pentacoordinated germanium and an iron atom

AU - Kano, Naokazu

AU - Yoshinari, Naohito

AU - Shibata, Yusuke

AU - Miyachi, Mariko

AU - Kawashima, Takayuki

AU - Enomoto, Masaya

AU - Okazawa, Atsushi

AU - Kojima, Norimichi

AU - Guo, Jing Dong

AU - Nagase, Shigeru

PY - 2012/12/10

Y1 - 2012/12/10

N2 - The first stable anionic iron(0) complexes bearing an ate-type pentacoordinated germanium(IV) ligand were synthesized. The X-ray crystallographic analysis shows trigonal-bipyramidal and piano-stool geometries of germanium and iron, respectively. The complexes have moderately electron-rich iron centers and polar Ge-Fe bonds which can be cleaved by oxidation.

AB - The first stable anionic iron(0) complexes bearing an ate-type pentacoordinated germanium(IV) ligand were synthesized. The X-ray crystallographic analysis shows trigonal-bipyramidal and piano-stool geometries of germanium and iron, respectively. The complexes have moderately electron-rich iron centers and polar Ge-Fe bonds which can be cleaved by oxidation.

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U2 - 10.1021/om300915y

DO - 10.1021/om300915y

M3 - Article

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JO - Organometallics

JF - Organometallics

IS - 23

ER -

Anionic iron complexes with a bond between an ate-type pentacoordinated germanium and an iron atom

Abstract

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