Anisotropy of alkyl chains of azobenzene molecules at the air/water interface observed by sum-frequency vibrational spectroscopy

Masahito Oh-e, Yuka Tabe, Hiroshi Yokoyama

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The structure of alkyl chains of azobenzene molecules at the air/water interface was studied using surface-specific sum-frequency vibrational spectroscopy. It was shown that the alkyl chains were well aligned before ultraviolet (UV) irradiation and protruding out of the surface with a certain distribution. The alkyl chains become less ordered by UV irradiation following dynamical motion due to cis-trans isomerization of azobenzene core. The alkyl chains show anisotropy in the direction perpendicular to that of the azobenzene core by linearly polarized UV irradiation.

Original languageEnglish
Article number061602
Pages (from-to)616021-616026
Number of pages6
JournalPhysical Review E - Statistical, Nonlinear, and Soft Matter Physics
Volume68
Issue number6 1
Publication statusPublished - 2003 Dec
Externally publishedYes

Fingerprint

Azobenzene
Anisotropy
Spectroscopy
Molecules
Ultraviolet
Irradiation
Water
anisotropy
irradiation
air
water
spectroscopy
molecules
isomerization
Perpendicular
Linearly
Motion

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Condensed Matter Physics
  • Statistical and Nonlinear Physics
  • Mathematical Physics

Cite this

Anisotropy of alkyl chains of azobenzene molecules at the air/water interface observed by sum-frequency vibrational spectroscopy. / Oh-e, Masahito; Tabe, Yuka; Yokoyama, Hiroshi.

In: Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, Vol. 68, No. 6 1, 061602, 12.2003, p. 616021-616026.

Research output: Contribution to journalArticle

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