Application of electrochemically formed polypyrrole in lithium secondary batteries

Analysis of anion diffusion process

K. Naoi, H. Sakai, S. Ogano, Tetsuya Osaka

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

A long cycle-life has been obtained with an Li/LiClO4-propylene carbonate (PC)/polypyrrole (PPy) battery when a PPy film formed in LiPF6/PC by electro-oxidative polymerization is used in an LiClO4/PC electrolyte after undoping PF6 - anions. The apparent diffusion coefficients of anions within the PPy film and the impedance spectra for PPy film electrodes are strongly dependent upon the film formation conditions. Electrolyte anions used in the film formation, which influence the morphology of the polymer film, have been found to play an important role in determining the electrochemical process and the cycle life of the Li/PPy battery.

Original languageEnglish
Pages (from-to)237-242
Number of pages6
JournalJournal of Power Sources
Volume20
Issue number3-4
DOIs
Publication statusPublished - 1987

Fingerprint

storage batteries
Secondary batteries
lithium batteries
polypyrroles
Polypyrroles
Lithium
Anions
Negative ions
anions
Propylene
Carbonates
propylene
carbonates
Electrolytes
Life cycle
electric batteries
electrolytes
cycles
Polymer films
Polymerization

ASJC Scopus subject areas

  • Electrochemistry
  • Fuel Technology
  • Materials Chemistry

Cite this

Application of electrochemically formed polypyrrole in lithium secondary batteries : Analysis of anion diffusion process. / Naoi, K.; Sakai, H.; Ogano, S.; Osaka, Tetsuya.

In: Journal of Power Sources, Vol. 20, No. 3-4, 1987, p. 237-242.

Research output: Contribution to journalArticle

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