Application of Ir-base alloys to novel oxidation resistant bond-coatings

Hideyuki Murakami, A. Suzuki, F. Wu, P. Kuppusami, H. Harada

Research output: Contribution to conferencePaper

4 Citations (Scopus)

Abstract

High temperature oxidation and hot corrosion properties of Ir-Ta, Ir-Pt coated and aluminized coatings are presented. An Ir-Ta binary alloy, proposed as a novel metallic bond coat material, was coated on a Ni-base single crystal superalloy TMS-75 using electron beam physical vapor deposition (EB-PVD), followed by a conventional Al pack cementation process. Cyclic oxidation tests and hot corrosion tests revealed that these Ir-Ta coated and aluminized specimens showed reasonably good oxidation and hot corrosion resistance. In addition, the formation of TCP phases is suppressed by the presence of the Ir-Ta enriched layer. These results indicated that the Ir-Ta alloy system is promising as a new metallic bond coat for high temperature structural materials. On the other hand, substitution of Pt with Ir in Pt-Al coatings is of interest for cost reduction and strengtheneing purposes. Cyclic oxidation properties of (Ir, Pt)-coatings, which were successfully electrodeposited on TMS-75, followed by aluminization, were also investigated. Cyclic oxidation tests at 1373 K in air revealed that materials having better thermal cyclic oxidation resistance can be arranged in the following order: Pt-Al = (36at%Ir, Pt)-Al > Ir-Al ≫ simply aluminized. The presence of Ir and/or Pt may promote the formation of dense and adherent oxide scale and thus retard the growth of thermally grown oxides. Ir addition is thus promising, not just in terms of cost reduction, but also expected solid solution strengthening.

Original languageEnglish
Pages589-596
Number of pages8
Publication statusPublished - 2004 Dec 1
Externally publishedYes
EventSUPERALLOYS 2004 - Tenth International Symposium on Superalloys - Champion, PA, United States
Duration: 2004 Sep 192004 Sep 23

Other

OtherSUPERALLOYS 2004 - Tenth International Symposium on Superalloys
CountryUnited States
CityChampion, PA
Period04/9/1904/9/23

Fingerprint

Coatings
Oxidation
Cost reduction
Oxides
Corrosion
Coated materials
Thermooxidation
Binary alloys
Oxidation resistance
Physical vapor deposition
Superalloys
Corrosion resistance
Electron beams
Solid solutions
Substitution reactions
Single crystals
Air
Temperature
Hot Temperature

Keywords

  • Bond-coat
  • EB-PVD
  • Electrodeposition
  • Ir-Pt
  • Ir-Ta

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Murakami, H., Suzuki, A., Wu, F., Kuppusami, P., & Harada, H. (2004). Application of Ir-base alloys to novel oxidation resistant bond-coatings. 589-596. Paper presented at SUPERALLOYS 2004 - Tenth International Symposium on Superalloys, Champion, PA, United States.

Application of Ir-base alloys to novel oxidation resistant bond-coatings. / Murakami, Hideyuki; Suzuki, A.; Wu, F.; Kuppusami, P.; Harada, H.

2004. 589-596 Paper presented at SUPERALLOYS 2004 - Tenth International Symposium on Superalloys, Champion, PA, United States.

Research output: Contribution to conferencePaper

Murakami, H, Suzuki, A, Wu, F, Kuppusami, P & Harada, H 2004, 'Application of Ir-base alloys to novel oxidation resistant bond-coatings', Paper presented at SUPERALLOYS 2004 - Tenth International Symposium on Superalloys, Champion, PA, United States, 04/9/19 - 04/9/23 pp. 589-596.
Murakami H, Suzuki A, Wu F, Kuppusami P, Harada H. Application of Ir-base alloys to novel oxidation resistant bond-coatings. 2004. Paper presented at SUPERALLOYS 2004 - Tenth International Symposium on Superalloys, Champion, PA, United States.
Murakami, Hideyuki ; Suzuki, A. ; Wu, F. ; Kuppusami, P. ; Harada, H. / Application of Ir-base alloys to novel oxidation resistant bond-coatings. Paper presented at SUPERALLOYS 2004 - Tenth International Symposium on Superalloys, Champion, PA, United States.8 p.
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N2 - High temperature oxidation and hot corrosion properties of Ir-Ta, Ir-Pt coated and aluminized coatings are presented. An Ir-Ta binary alloy, proposed as a novel metallic bond coat material, was coated on a Ni-base single crystal superalloy TMS-75 using electron beam physical vapor deposition (EB-PVD), followed by a conventional Al pack cementation process. Cyclic oxidation tests and hot corrosion tests revealed that these Ir-Ta coated and aluminized specimens showed reasonably good oxidation and hot corrosion resistance. In addition, the formation of TCP phases is suppressed by the presence of the Ir-Ta enriched layer. These results indicated that the Ir-Ta alloy system is promising as a new metallic bond coat for high temperature structural materials. On the other hand, substitution of Pt with Ir in Pt-Al coatings is of interest for cost reduction and strengtheneing purposes. Cyclic oxidation properties of (Ir, Pt)-coatings, which were successfully electrodeposited on TMS-75, followed by aluminization, were also investigated. Cyclic oxidation tests at 1373 K in air revealed that materials having better thermal cyclic oxidation resistance can be arranged in the following order: Pt-Al = (36at%Ir, Pt)-Al > Ir-Al ≫ simply aluminized. The presence of Ir and/or Pt may promote the formation of dense and adherent oxide scale and thus retard the growth of thermally grown oxides. Ir addition is thus promising, not just in terms of cost reduction, but also expected solid solution strengthening.

AB - High temperature oxidation and hot corrosion properties of Ir-Ta, Ir-Pt coated and aluminized coatings are presented. An Ir-Ta binary alloy, proposed as a novel metallic bond coat material, was coated on a Ni-base single crystal superalloy TMS-75 using electron beam physical vapor deposition (EB-PVD), followed by a conventional Al pack cementation process. Cyclic oxidation tests and hot corrosion tests revealed that these Ir-Ta coated and aluminized specimens showed reasonably good oxidation and hot corrosion resistance. In addition, the formation of TCP phases is suppressed by the presence of the Ir-Ta enriched layer. These results indicated that the Ir-Ta alloy system is promising as a new metallic bond coat for high temperature structural materials. On the other hand, substitution of Pt with Ir in Pt-Al coatings is of interest for cost reduction and strengtheneing purposes. Cyclic oxidation properties of (Ir, Pt)-coatings, which were successfully electrodeposited on TMS-75, followed by aluminization, were also investigated. Cyclic oxidation tests at 1373 K in air revealed that materials having better thermal cyclic oxidation resistance can be arranged in the following order: Pt-Al = (36at%Ir, Pt)-Al > Ir-Al ≫ simply aluminized. The presence of Ir and/or Pt may promote the formation of dense and adherent oxide scale and thus retard the growth of thermally grown oxides. Ir addition is thus promising, not just in terms of cost reduction, but also expected solid solution strengthening.

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