Aromatic C-H coupling with hindered arylboronic acids by Pd/Fe dual catalysts

Kazuya Yamaguchi, Hiroki Kondo, Junichiro Yamaguchi, Kenichiro Itami

Research output: Contribution to journalArticle

73 Citations (Scopus)

Abstract

An aerobic oxidative coupling of arenes/alkenes with arylboronic acids (C-H/C-B coupling) using catalytic Pd(ii)-sulfoxide-oxazoline (sox) ligand and iron-phthalocyanine (FePc) has been developed. This dual catalyst system enables the synthesis of sterically hindered heterobiaryls and styrene derivatives under air without stoichiometric co-oxidants. Additionally, this chemistry demonstrated an advance toward an enantioselective biaryl coupling through C-H functionalization.

Original languageEnglish
Pages (from-to)3753-3757
Number of pages5
JournalChemical Science
Volume4
Issue number9
DOIs
Publication statusPublished - 2013 Sep
Externally publishedYes

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sulfoxide
Styrene
Alkenes
Oxidants
Ligands
Derivatives
Catalysts
Acids
Air
iron phthalocyanine

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Aromatic C-H coupling with hindered arylboronic acids by Pd/Fe dual catalysts. / Yamaguchi, Kazuya; Kondo, Hiroki; Yamaguchi, Junichiro; Itami, Kenichiro.

In: Chemical Science, Vol. 4, No. 9, 09.2013, p. 3753-3757.

Research output: Contribution to journalArticle

Yamaguchi, Kazuya ; Kondo, Hiroki ; Yamaguchi, Junichiro ; Itami, Kenichiro. / Aromatic C-H coupling with hindered arylboronic acids by Pd/Fe dual catalysts. In: Chemical Science. 2013 ; Vol. 4, No. 9. pp. 3753-3757.
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