Arrangements of interlayer quaternary ammonium ions in a layered silicate, octosilicate

Makoto Ogawa, Daisuke Iwata

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

The ion exchange of octosilicate with a series of quaternary organoammonium ions was examined. The ion exchange proceeds almost quantitatively to replace the interlayer sodium ions. When n-alkyltrimethylammonium ions were exchanged with sodium ions, the basal spacings increased with the alkyl chain length, showing the formation of paraffin type surfactant aggregates in the interlayer space. When the organic cations with complex molecular geometry (dimethyldioctadecylammonium, N-(α-trimethylammonioacetyl)-didodecyl-l- glutamate, and O,O',O"-tridodecanoyl-N-(ω-trimethyl ammoniodecanoyl)-tris(hydroxymethyl)aminomethane) were used, the basal spacings changed as a function of the molecular weight of the intercalated guest species. It is speculated that the molecular geometries of the intercalated species are flexible to form densely packed nanostructures in the interlayer space.

Original languageEnglish
Pages (from-to)2068-2072
Number of pages5
JournalCrystal Growth and Design
Volume10
Issue number5
DOIs
Publication statusPublished - 2010 May 5

Fingerprint

Silicates
Ammonium Compounds
interlayers
silicates
Ions
Ion exchange
ions
Sodium
Tromethamine
Geometry
Chain length
spacing
sodium
Surface-Active Agents
Paraffin
Paraffins
Cations
Glutamic Acid
Nanostructures
glutamates

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Arrangements of interlayer quaternary ammonium ions in a layered silicate, octosilicate. / Ogawa, Makoto; Iwata, Daisuke.

In: Crystal Growth and Design, Vol. 10, No. 5, 05.05.2010, p. 2068-2072.

Research output: Contribution to journalArticle

Ogawa, Makoto ; Iwata, Daisuke. / Arrangements of interlayer quaternary ammonium ions in a layered silicate, octosilicate. In: Crystal Growth and Design. 2010 ; Vol. 10, No. 5. pp. 2068-2072.
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