Abstract
This chapter summarizes the recent work (published after 2000) of enantioseletive cycloadditions catalyzed by chiral Lewis acids and chiral transition metal complexes. The cycloaddition is categorized as [4+2], [5+2], [2+2], [2+2+2], [3+2], and [4+3] cycloadditions. These reactions provide efficient protocols for the construction of various chiral cyclic skeletons, which include central, axial, planar, and helical chiralities.
| Original language | English |
|---|---|
| Title of host publication | Comprehensive Inorganic Chemistry II (Second Edition) |
| Subtitle of host publication | From Elements to Applications |
| Publisher | Elsevier Ltd |
| Pages | 249-269 |
| Number of pages | 21 |
| Volume | 6 |
| ISBN (Print) | 9780080965291 |
| DOIs | |
| Publication status | Published - 2013 Aug 1 |
Keywords
- Catalyst
- Chirality
- Cycloaddition
- Enantioselective
- Lewis Acids
- Transition Metals
ASJC Scopus subject areas
- Chemistry(all)
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Cite this
Shibata, T. (2013). Asymmetric Cycloaddition Reactions. In Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications (Vol. 6, pp. 249-269). Elsevier Ltd. https://doi.org/10.1016/B978-0-08-097774-4.00612-4