Asymmetric Cycloaddition Reactions

T. Shibata

doi:10.1016/B978-0-08-097774-4.00612-4

Asymmetric Cycloaddition Reactions

T. Shibata

School of Advanced Science and Engineering

Research output: Chapter in Book/Report/Conference proceeding › Chapter

3 Citations (Scopus)

Abstract

This chapter summarizes the recent work (published after 2000) of enantioseletive cycloadditions catalyzed by chiral Lewis acids and chiral transition metal complexes. The cycloaddition is categorized as [4+2], [5+2], [2+2], [2+2+2], [3+2], and [4+3] cycloadditions. These reactions provide efficient protocols for the construction of various chiral cyclic skeletons, which include central, axial, planar, and helical chiralities.

Original language	English
Title of host publication	Comprehensive Inorganic Chemistry II (Second Edition)
Subtitle of host publication	From Elements to Applications
Publisher	Elsevier Ltd
Pages	249-269
Number of pages	21
Volume	6
ISBN (Print)	9780080965291
DOIs	https://doi.org/10.1016/B978-0-08-097774-4.00612-4
Publication status	Published - 2013 Aug 1

Keywords

Catalyst
Chirality
Cycloaddition
Enantioselective
Lewis Acids
Transition Metals

ASJC Scopus subject areas

Chemistry(all)

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10.1016/B978-0-08-097774-4.00612-4

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AB - This chapter summarizes the recent work (published after 2000) of enantioseletive cycloadditions catalyzed by chiral Lewis acids and chiral transition metal complexes. The cycloaddition is categorized as [4+2], [5+2], [2+2], [2+2+2], [3+2], and [4+3] cycloadditions. These reactions provide efficient protocols for the construction of various chiral cyclic skeletons, which include central, axial, planar, and helical chiralities.

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KW - Chirality

KW - Cycloaddition

KW - Enantioselective

KW - Lewis Acids

KW - Transition Metals

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