Asymmetric synthesis of N-(diphenylphosphinyl)-ferrocenylamine by the enantioselective alkylation of ferrocenylimine

Tadakatsu Hayase, Yukikazu Inoue, Takanori Shibata, Kenso Soai

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Abstract

Optically active N-(diphenylphosphinyl)ferrocenylamines with good to high e.e.'s were obtained by the enantioselective addition of dialkylzincs to ferrocenyl-diphenylphosphinylimine in the presence of chiral β-aminoalcohols. The subsequent hydrolysis afforded a chiral ferrocenylamine without racemization.

Original languageEnglish
Pages (from-to)2509-2510
Number of pages2
JournalTetrahedron Asymmetry
Volume7
Issue number9
DOIs
Publication statusPublished - 1996 Sep

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ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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