Asymmetric synthesis of N-(diphenylphosphinyl)-ferrocenylamine by the enantioselective alkylation of ferrocenylimine

Tadakatsu Hayase, Yukikazu Inoue, Takanori Shibata, Kenso Soai

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Optically active N-(diphenylphosphinyl)ferrocenylamines with good to high e.e.'s were obtained by the enantioselective addition of dialkylzincs to ferrocenyl-diphenylphosphinylimine in the presence of chiral β-aminoalcohols. The subsequent hydrolysis afforded a chiral ferrocenylamine without racemization.

Original languageEnglish
Pages (from-to)2509-2510
Number of pages2
JournalTetrahedron Asymmetry
Volume7
Issue number9
DOIs
Publication statusPublished - 1996 Sep
Externally publishedYes

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alkylation
Alkylation
hydrolysis
Hydrolysis
synthesis

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Materials Chemistry
  • Drug Discovery

Cite this

Asymmetric synthesis of N-(diphenylphosphinyl)-ferrocenylamine by the enantioselective alkylation of ferrocenylimine. / Hayase, Tadakatsu; Inoue, Yukikazu; Shibata, Takanori; Soai, Kenso.

In: Tetrahedron Asymmetry, Vol. 7, No. 9, 09.1996, p. 2509-2510.

Research output: Contribution to journalArticle

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