Average octet radical polymer: A stable polyphenoxyl with star-shaped π conjugation

Hiroyuki Nishide; Makoto Miyasaka; Eishun Tsuchida

doi:10.1002/(SICI)1521-3773(19980918)37:17<2400::AID-ANIE2400>3.0.CO;2-0

Average octet radical polymer: A stable polyphenoxyl with star-shaped π conjugation

Hiroyuki Nishide^*, Makoto Miyasaka, Eishun Tsuchida

^*Corresponding author for this work

Waseda Research Institute for Science and Engineering

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

An average spin quantum number of 7/2 is displayed by the star-shaped, π-conjugated polyradical 1, even with a spin concentration of 0.8 per monomer unit. Polymer 1 is stable at room temperature, and it is a powerful candidate for the synthesis of a feasible polymer with very high spin.

Original language	English
Pages (from-to)	2400-2402
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	37
Issue number	17
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19980918)37:17<2400::AID-ANIE2400>3.0.CO;2-0
Publication status	Published - 1998 Sept 18

Keywords

EPR spectroscopy
Magnetic properties
Polymers
Polyradicals
Radicals

ASJC Scopus subject areas

Chemistry(all)

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10.1002/(SICI)1521-3773(19980918)37:17<2400::AID-ANIE2400>3.0.CO;2-0

Cite this

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keywords = "EPR spectroscopy, Magnetic properties, Polymers, Polyradicals, Radicals",

author = "Hiroyuki Nishide and Makoto Miyasaka and Eishun Tsuchida",

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T2 - A stable polyphenoxyl with star-shaped π conjugation

AU - Nishide, Hiroyuki

AU - Miyasaka, Makoto

AU - Tsuchida, Eishun

PY - 1998/9/18

Y1 - 1998/9/18

N2 - An average spin quantum number of 7/2 is displayed by the star-shaped, π-conjugated polyradical 1, even with a spin concentration of 0.8 per monomer unit. Polymer 1 is stable at room temperature, and it is a powerful candidate for the synthesis of a feasible polymer with very high spin.

AB - An average spin quantum number of 7/2 is displayed by the star-shaped, π-conjugated polyradical 1, even with a spin concentration of 0.8 per monomer unit. Polymer 1 is stable at room temperature, and it is a powerful candidate for the synthesis of a feasible polymer with very high spin.

KW - EPR spectroscopy

KW - Magnetic properties

KW - Polymers

KW - Polyradicals

KW - Radicals

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Average octet radical polymer: A stable polyphenoxyl with star-shaped π conjugation

Abstract

Keywords

ASJC Scopus subject areas

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