BARF-catalyzed C-H bond alkenylation and alkylation of ferrocenes

Satoshi Takebayashi; Takanori Shibata

doi:10.1021/om300348e

BARF-catalyzed C-H bond alkenylation and alkylation of ferrocenes

Satoshi Takebayashi, Takanori Shibata^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

73 Citations (Scopus)

Abstract

[Ir(cod) ₂]BARF [BARF = tetrakis(3,5-trifluoromethylphenyl) borate] catalyzed the directed alkenylation and alkylation of ferrocenes to form a variety of tri- and disubstituted ferrocenes. Mechanistic investigation revealed several putative intermediates along with the importance of COD (1,5-cyclooctadiene), as a diene ligand, and a possible catalyst deactivation pathway. On the basis of the mechanistic investigation, catalytic activity was further improved.

Original language	English
Pages (from-to)	4114-4117
Number of pages	4
Journal	Organometallics
Volume	31
Issue number	11
DOIs	https://doi.org/10.1021/om300348e
Publication status	Published - 2012 Jun 11

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "[Ir(cod) 2]BARF [BARF = tetrakis(3,5-trifluoromethylphenyl) borate] catalyzed the directed alkenylation and alkylation of ferrocenes to form a variety of tri- and disubstituted ferrocenes. Mechanistic investigation revealed several putative intermediates along with the importance of COD (1,5-cyclooctadiene), as a diene ligand, and a possible catalyst deactivation pathway. On the basis of the mechanistic investigation, catalytic activity was further improved.",

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AU - Shibata, Takanori

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N2 - [Ir(cod) 2]BARF [BARF = tetrakis(3,5-trifluoromethylphenyl) borate] catalyzed the directed alkenylation and alkylation of ferrocenes to form a variety of tri- and disubstituted ferrocenes. Mechanistic investigation revealed several putative intermediates along with the importance of COD (1,5-cyclooctadiene), as a diene ligand, and a possible catalyst deactivation pathway. On the basis of the mechanistic investigation, catalytic activity was further improved.

AB - [Ir(cod) 2]BARF [BARF = tetrakis(3,5-trifluoromethylphenyl) borate] catalyzed the directed alkenylation and alkylation of ferrocenes to form a variety of tri- and disubstituted ferrocenes. Mechanistic investigation revealed several putative intermediates along with the importance of COD (1,5-cyclooctadiene), as a diene ligand, and a possible catalyst deactivation pathway. On the basis of the mechanistic investigation, catalytic activity was further improved.

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BARF-catalyzed C-H bond alkenylation and alkylation of ferrocenes

Abstract

ASJC Scopus subject areas

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