BARF-catalyzed C-H bond alkenylation and alkylation of ferrocenes

Satoshi Takebayashi, Takanori Shibata

Research output: Contribution to journalArticle

59 Citations (Scopus)

Abstract

[Ir(cod) 2]BARF [BARF = tetrakis(3,5-trifluoromethylphenyl) borate] catalyzed the directed alkenylation and alkylation of ferrocenes to form a variety of tri- and disubstituted ferrocenes. Mechanistic investigation revealed several putative intermediates along with the importance of COD (1,5-cyclooctadiene), as a diene ligand, and a possible catalyst deactivation pathway. On the basis of the mechanistic investigation, catalytic activity was further improved.

Original languageEnglish
Pages (from-to)4114-4117
Number of pages4
JournalOrganometallics
Volume31
Issue number11
DOIs
Publication statusPublished - 2012 Jun 11

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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