BARF-catalyzed C-H bond alkenylation and alkylation of ferrocenes

Satoshi Takebayashi, Takanori Shibata

    Research output: Contribution to journalArticle

    55 Citations (Scopus)

    Abstract

    [Ir(cod) 2]BARF [BARF = tetrakis(3,5-trifluoromethylphenyl) borate] catalyzed the directed alkenylation and alkylation of ferrocenes to form a variety of tri- and disubstituted ferrocenes. Mechanistic investigation revealed several putative intermediates along with the importance of COD (1,5-cyclooctadiene), as a diene ligand, and a possible catalyst deactivation pathway. On the basis of the mechanistic investigation, catalytic activity was further improved.

    Original languageEnglish
    Pages (from-to)4114-4117
    Number of pages4
    JournalOrganometallics
    Volume31
    Issue number11
    DOIs
    Publication statusPublished - 2012 Jun 11

    Fingerprint

    Alkenylation
    ferrocenes
    Borates
    Catalyst deactivation
    alkylation
    Alkylation
    Catalyst activity
    Ligands
    dienes
    borates
    deactivation
    catalytic activity
    catalysts
    ligands
    1,5-cyclooctadiene

    ASJC Scopus subject areas

    • Organic Chemistry
    • Physical and Theoretical Chemistry
    • Inorganic Chemistry

    Cite this

    BARF-catalyzed C-H bond alkenylation and alkylation of ferrocenes. / Takebayashi, Satoshi; Shibata, Takanori.

    In: Organometallics, Vol. 31, No. 11, 11.06.2012, p. 4114-4117.

    Research output: Contribution to journalArticle

    Takebayashi, Satoshi ; Shibata, Takanori. / BARF-catalyzed C-H bond alkenylation and alkylation of ferrocenes. In: Organometallics. 2012 ; Vol. 31, No. 11. pp. 4114-4117.
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