Behaviour of Ir-24 at.-%Ta films on Ni based single crystal superalloys

P. Kuppusami, Hideyuki Murakami, T. Ohmura

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The properties of Ir-24Ta (at.-%) films prepared by dc magnetron cosputtering from a composite target on a 〈100〉 oriented Ni based single crystal superalloy TMS-75 were investigated. Ir-Ta was proposed as a novel oxidation resistant bond coat material for thermal barrier coatings. XRD showed the formation of a Ir3Ta fcc phase with a fibre texture with 〈111〉 orientation tilted by ∼ 10° with respect to the plane normal to the substrate surface. The Ir-Ta film subjected to post-heat treatment was found to be very stable, with no secondary phase formation up to 1073 K, and there seems to be interdiffusion at 1273 K. Nanoindentation measurements indicated that the addition of tantalum decreased Young's modulus and increased the hardness obtained in the as deposited films compared with the hardness of iridium films. The Ir-Ta films heat treated up to 1273 K also exhibited nanomechanical properties comparable with those of as deposited films at 573 K.

Original languageEnglish
Pages (from-to)53-59
Number of pages7
JournalSurface Engineering
Volume21
Issue number1
DOIs
Publication statusPublished - 2005 Feb 1
Externally publishedYes

Fingerprint

heat resistant alloys
Superalloys
Single crystals
single crystals
hardness
Hardness
Tantalum
Iridium
Thermal barrier coatings
Nanoindentation
tantalum
nanoindentation
iridium
Crystal
modulus of elasticity
heat treatment
textures
Textures
Elastic moduli
Heat treatment

Keywords

  • Atomic force microscopy
  • Crystallite size
  • Electron probe microanalyser
  • Iridium
  • Mechanical properties
  • Nanoindentation
  • Post-heat treatment
  • SEM
  • Sputtering
  • Superalloy
  • Tantalum
  • Texture
  • Thermal barrier coatings
  • Thin film
  • XRD

ASJC Scopus subject areas

  • Conservation
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Behaviour of Ir-24 at.-%Ta films on Ni based single crystal superalloys. / Kuppusami, P.; Murakami, Hideyuki; Ohmura, T.

In: Surface Engineering, Vol. 21, No. 1, 01.02.2005, p. 53-59.

Research output: Contribution to journalArticle

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