Benzene-Oxygen Reaction Over Alkaline Earth Metal Oxide Catalysts.

Masahiko Matsukata, Eiji Okanari, Eiichi Kikuchi, Yoshiro Morita

    Research output: Contribution to journalArticle

    Abstract

    The benzene-oxygen reaction catalyzed by alkaline earth metal oxides was investigated in the temperature range 773-1,073K to understand the catalytic function of these oxides for hydrocarbon gasification. In the initial stage of reaction, CO, CO2, H2O, and biphenyl were concurrently produced. The consumption of CO and H2O by the water-gas shift reaction subsequently occurred to give CO2and H2. CO oxidation with O2hardly occurred in the course of the benzene-oxygen reaction because benzene was preferentially adsorbed on the MgO catalyst. These reaction sequences were compared with those in the benzene-oxygen reaction catalyzed by metallic nickel.

    Original languageEnglish
    Pages (from-to)36-43
    Number of pages8
    JournalSekiyu Gakkaishi (Journal of the Japan Petroleum Institute)
    Volume34
    Issue number1
    DOIs
    Publication statusPublished - 1991

    Fingerprint

    Alkaline earth metals
    Benzene
    Catalysts
    Oxides
    Oxygen
    Water gas shift
    Gasification
    Hydrocarbons
    Nickel
    Oxidation
    Temperature

    ASJC Scopus subject areas

    • Fuel Technology

    Cite this

    Benzene-Oxygen Reaction Over Alkaline Earth Metal Oxide Catalysts. / Matsukata, Masahiko; Okanari, Eiji; Kikuchi, Eiichi; Morita, Yoshiro.

    In: Sekiyu Gakkaishi (Journal of the Japan Petroleum Institute), Vol. 34, No. 1, 1991, p. 36-43.

    Research output: Contribution to journalArticle

    Matsukata, Masahiko ; Okanari, Eiji ; Kikuchi, Eiichi ; Morita, Yoshiro. / Benzene-Oxygen Reaction Over Alkaline Earth Metal Oxide Catalysts. In: Sekiyu Gakkaishi (Journal of the Japan Petroleum Institute). 1991 ; Vol. 34, No. 1. pp. 36-43.
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