Bioprotectant glassforming solutions confined in porous silicon nanocapillaries

Rémi Busselez, Ronan Lefort, Qing Ji, Regis Guegan, Gilbert Chahine, Mohammed Guendouz, Jean Marc Zanotti, Bernhard Frick, D. Morineau

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Glycerol and trehalose-glycerol binary solutions are glass-forming liquids with remarkable bioprotectant properties. In this paper, we address the effects of confining of these solutions in straight channels of diameter D=8 nm formed by porous silicon. Neutron diffraction and incoherent quasielastic neutron scattering are used to reveal the different effects of nanoconfinement and addition of trehalose on the intermolecular structure and molecular dynamics of the liquid and glassy phases, on a nanosecond timescale.

Original languageEnglish
Title of host publicationLocal Structure and Dynamics in Amorphous Systems
Pages85-90
Number of pages6
Volume1152
Publication statusPublished - 2008 Dec 1
Externally publishedYes
Event2008 MRS Fall Meeting - Boston, MA
Duration: 2008 Dec 12008 Dec 5

Other

Other2008 MRS Fall Meeting
CityBoston, MA
Period08/12/108/12/5

Fingerprint

Trehalose
Porous silicon
glycerols
porous silicon
Glycerol
Incoherent scattering
incoherent scattering
Liquids
Neutron diffraction
Neutron scattering
confining
neutron diffraction
Molecular dynamics
liquid phases
neutron scattering
molecular dynamics
Glass
glass
liquids

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Busselez, R., Lefort, R., Ji, Q., Guegan, R., Chahine, G., Guendouz, M., ... Morineau, D. (2008). Bioprotectant glassforming solutions confined in porous silicon nanocapillaries. In Local Structure and Dynamics in Amorphous Systems (Vol. 1152, pp. 85-90)

Bioprotectant glassforming solutions confined in porous silicon nanocapillaries. / Busselez, Rémi; Lefort, Ronan; Ji, Qing; Guegan, Regis; Chahine, Gilbert; Guendouz, Mohammed; Zanotti, Jean Marc; Frick, Bernhard; Morineau, D.

Local Structure and Dynamics in Amorphous Systems. Vol. 1152 2008. p. 85-90.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Busselez, R, Lefort, R, Ji, Q, Guegan, R, Chahine, G, Guendouz, M, Zanotti, JM, Frick, B & Morineau, D 2008, Bioprotectant glassforming solutions confined in porous silicon nanocapillaries. in Local Structure and Dynamics in Amorphous Systems. vol. 1152, pp. 85-90, 2008 MRS Fall Meeting, Boston, MA, 08/12/1.
Busselez R, Lefort R, Ji Q, Guegan R, Chahine G, Guendouz M et al. Bioprotectant glassforming solutions confined in porous silicon nanocapillaries. In Local Structure and Dynamics in Amorphous Systems. Vol. 1152. 2008. p. 85-90
Busselez, Rémi ; Lefort, Ronan ; Ji, Qing ; Guegan, Regis ; Chahine, Gilbert ; Guendouz, Mohammed ; Zanotti, Jean Marc ; Frick, Bernhard ; Morineau, D. / Bioprotectant glassforming solutions confined in porous silicon nanocapillaries. Local Structure and Dynamics in Amorphous Systems. Vol. 1152 2008. pp. 85-90
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