Biphasic synthesis of colloidal mesoporous silica nanoparticles using primary amine catalysts

Junzheng Wang, Ayae Sugawara-Narutaki, Atsushi Shimojima, Tatsuya Okubo

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A new type of colloidal mesoporous silica nanoparticles (MSNs) is synthesized in liquid-liquid biphasic systems consisting of tetraethoxysilane (TEOS) and water in the presence of primary amines and cationic surfactants (cetyltrimethylammonium chloride, CTAC) under controlled pH conditions (pH 11.1-11.5). The obtained MSNs are characterized by scanning electron microscopy (SEM), scanning transmission electron microscopy (STEM), X-ray diffraction (XRD), and nitrogen adsorption-desorption. The results show that the colloidal MSNs with an average diameter in the range of 28-54nm and a size polydispersity below ca. 15% have been obtained. Importantly, each MSN is composed of a number of tiny primary silica nanoparticles (PSNPs) forming 3D connected pore structure. The pore size of the MSNs can be tuned from 2.5 to 3.0nm by changing the pH of catalyst stock solution, and larger pore sizes (3.1-4.5nm) can be achieved by using pore swelling agent. The Brunauer-Emmett-Teller (BET) surface areas and total pore volumes vary from 550 to 750m 2g -1 and from 1.2 to 1.7cm 3g -1, respectively. Compared with conventional MCM-41-type MSNs, our new MSNs show outstanding colloidal and hydrothermal stabilities. They are colloidally stable at room temperature over 1year, and their mesostructure was retained even after hydrothermal treatment at 120°C for 24h. Finally, based on the analysis of the morphology and structure of MSNs, a formation scheme based on the cooperative self-assembly of PSNPs and surfactant molecules is proposed.

Original languageEnglish
Pages (from-to)41-47
Number of pages7
JournalJournal of Colloid and Interface Science
Volume385
Issue number1
DOIs
Publication statusPublished - 2012 Nov 1
Externally publishedYes

Fingerprint

Silicon Dioxide
Amines
Silica
Nanoparticles
Catalysts
Pore size
Scanning electron microscopy
Cationic surfactants
Liquids
Polydispersity
Multicarrier modulation
Pore structure
Surface-Active Agents
Self assembly
Swelling
Desorption
Surface active agents
Nitrogen
Transmission electron microscopy
Adsorption

Keywords

  • Colloid
  • Mesoporous silica nanoparticles
  • Primary amine

ASJC Scopus subject areas

  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Colloid and Surface Chemistry

Cite this

Biphasic synthesis of colloidal mesoporous silica nanoparticles using primary amine catalysts. / Wang, Junzheng; Sugawara-Narutaki, Ayae; Shimojima, Atsushi; Okubo, Tatsuya.

In: Journal of Colloid and Interface Science, Vol. 385, No. 1, 01.11.2012, p. 41-47.

Research output: Contribution to journalArticle

Wang, Junzheng ; Sugawara-Narutaki, Ayae ; Shimojima, Atsushi ; Okubo, Tatsuya. / Biphasic synthesis of colloidal mesoporous silica nanoparticles using primary amine catalysts. In: Journal of Colloid and Interface Science. 2012 ; Vol. 385, No. 1. pp. 41-47.
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