TY - JOUR
T1 - C-H Borylation of Arenes
T2 - Steric-controlled Para-selectivity and Application to Molecular Nanocarbons
AU - Segawa, Yasutomo
AU - Nagase, Mai
AU - Saito, Yutaro
AU - Kato, Kenta
AU - Itami, Kenichiro
N1 - Funding Information:
The authors would like to express their appreciation to all past and present members of the research group at Nagoya University for their vital contributions. M.N. gives thanks for SRA financial support for outstanding students in IMS, and a JSPS fellowship for young scientists. Y.Se. acknowledges the JST-FOREST program (JPMJFR211R). ITbM is supported by the World Premier International Research Center (WPI) Initiative, Japan.
Funding Information:
The authors would like to express their appreciation to all past and present members of the research group at Nagoya University for their vital contributions. M.N. gives thanks for SRA financial support for outstanding students in IMS, and a JSPS fellowship for young scientists. Y.Se. acknowledges the JST─FOREST program (JPMJFR211R). ITbM is supported by the World Premier International Research Center (WPI) Initiative, Japan.
Publisher Copyright:
© 2022 Society of Synthetic Organic Chemistry. All rights reserved.
PY - 2022
Y1 - 2022
N2 - The selective and predictable C-H functionalization of arenes is a valuable method for the synthesis and modification of organic molecules in which regioisomer formation is often controlled by electronic factors or the presence of coordinating groups. On the other hand, the iridium-catalyzed C-H borylation of arenes can achieve unique steric-controlled regioselectivity. In this account, we describe our recent studies on the iridium-catalyzed C-H borylation of arenes: the development of novel catalytic systems that exhibit steric-controlled para-selectivity for mono-and unsymmetrically 1,2-disubstituted benzenes; and their application to the functionalization of large polycyclic aromatic hydrocarbons (molecular nanocarbons).
AB - The selective and predictable C-H functionalization of arenes is a valuable method for the synthesis and modification of organic molecules in which regioisomer formation is often controlled by electronic factors or the presence of coordinating groups. On the other hand, the iridium-catalyzed C-H borylation of arenes can achieve unique steric-controlled regioselectivity. In this account, we describe our recent studies on the iridium-catalyzed C-H borylation of arenes: the development of novel catalytic systems that exhibit steric-controlled para-selectivity for mono-and unsymmetrically 1,2-disubstituted benzenes; and their application to the functionalization of large polycyclic aromatic hydrocarbons (molecular nanocarbons).
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U2 - 10.5059/YUKIGOSEIKYOKAISHI.80.994
DO - 10.5059/YUKIGOSEIKYOKAISHI.80.994
M3 - Article
AN - SCOPUS:85142745766
VL - 80
SP - 994
EP - 999
JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
JF - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
SN - 0037-9980
IS - 11
ER -