Carbonylative and hydrosilylative carbocyclization of 1,5-diynes for the synthesis of cyclic dienones

Takanori Shibata, Naohisa Nakagawa, Yasunori Ueno, Kohei Endo

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A rhodium complex, [Rh(acac)(CO)2], has been identified to catalyze the cyclization of various 1,5-diynes with hydrosilanes under an atmospheric pressure of carbon monoxide at room temperature. The cyclization of 1,5-diynes proceeds along with hydrosilylation and carbonylation to give derivatives of 2,5-dialkylidenecyclopentanone.

Original languageEnglish
Pages (from-to)1342-1344
Number of pages3
JournalOrganometallics
Volume27
Issue number6
DOIs
Publication statusPublished - 2008 Mar 24

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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